Institut für Anorganische Chemie

Publications

241.

C. O. Hollfelder, L. N. Jende, D. Diether, C. Maichle-Mössmer, and R. Anwander

1,3-Diene Polymerization Promoted by Half-Sandwich Rare-Earth Metal Dimethyl Complexes: Active Species Clustering and Cationization/Deactivation Processes

Chem. Eur. J. 10.1002/chem.201901269.

240.

B. M. Wolf and R. Anwander

Chasing Multiple Bonding Interactions Between Alkaline-Earth Metals and Main-Group Fragments

Chem. Eur. J. 10.1002/chem.201901169.

239.

M. Bonath, C. Maichle-Mössmer, P. Sirsch, and R. Anwander

Gallium Methylene

Angew. Chem. Int. Ed. 10.1002/anie.201902063; Angew. Chem. 10.1002/ange.201902063.

238.

B. M. Wolf, C. Stuhl, C. Maichle-Mössmer, and R. Anwander

Calcium Tetraalkylaluminate and Tetramethylgallate Complexes Supported by the Bulky Scorpionate Ligand TptBu,Me

Organometallics 2019, 38, 1614–1621.

237.

D. Barisic, D. A. Buschmann, D. Schneider, C. Maichle-Mössmer, and R. Anwander

Rare-Earth Metal Pentadienyl Half-Sandwich and Sandwich Tetramethylaluminates – Synthesis, Structure, Reactivity, and Performance in Isoprene Polymerization

Chem. Eur. J. 2019, 25, 4821–4832.Link

236.

J. Ilsemann, A. Sonström, T. M. Gesing, R. Anwander, and M. Bäumer

Highly active Sm2O3-Ni xerogel catalysts for CO2 methanation

ChemCatChem. 2019, 11, 1732–1741.Link

235.

A. Sonström, D. Schneider, C. Maichle-Mössmer, and R. Anwander

Titanium(IV) Catecholate-grafted Mesoporous Silica KIT-6: Probing Sequential and Convergent Immobilization Approaches

Eur. J. Inorg. Chem. 2019, 682–692.Link

234.

D. Barisic, D. Schneider, C. Maichle-Mössmer, and R. Anwander

Formation and Reactivity of an Aluminabenzene Ligand at Pentadienyl-Supported Rare-Earth-Metals

Angew. Chem. Int. Ed. 2019, 58, 1515–1518; Angew. Chem. 2019, 131, 1528–1532.Link
233.

R. Thim, D. Schädle, C. Maichle-Mössmer, and R. Anwander

Rare-Earth Metal Diimide Complexes via Alkylaluminate Templating, including a Ceric Derivative

Chem. Eur. J. 2019, 25, 507–511.Link

232.

J. Friedrich, C. Maichle-Mössmer, C. Schrenk, A. Schnepf, and R. Anwander

Ceric Ammonium Nitrate and Ceric Ammonium Chloride as Precursors for Ceric Siloxides: Ammonia and Ammonium Inclusion

Eur. J. Inorg. Chem. 2019, 79–90.Link

231.

C. Stuhl, M. Katzenmayer C. Maichle-Mössmer, and R. Anwander

Molecular Mg/Al-bimetallic hydrides

Dalton Trans. 2018, 47, 15173–15180.Link

230.

D. Werner and R. Anwander

Unveiling the Takai Olefination Reagent via Tris(tert-butoxy)siloxy Variants”,

J. Am. Chem. Soc. 2018, 140, 14334–14341.Link

229.

B. M. Wolf, C. Stuhl, C. Maichle-Mössmer, and R. Anwander

Lewis-Acid Stabilised Organoimide Complexes of Divalent Samarium, Europium, and Ytterbium

Chem. Eur. J. 2018, 24, 15921–15929.Link

228.

L. Luo, Y. Liang, T. Chassé, and R. Anwander

Ultrafast Adsorption of Myoglobin into Double-Shelled Hollow Mesoporous Silica Nanospheres

Part. Part. Syst. Charact. 2018, 24, 1800312.Link
227.

C. Stuhl, C. Maichle-Mössmer, and R. Anwander

Magnesium Stung by Non-Classical Scorpionate Ligands: Synthesis and Cone Angle-Calculations

Chem. Eur. J. 2018, 24, 14254–14268.Link

226.

D. Schneider, C. Maichle-Mössmer, and R. Anwander

Reactivity of Trivalent Ate-Complex Ce[N(SiHMe2)2]4Li(thf) toward 1,1,4,4-N,N,N’,N’-Tetramethylguanidine

Z. Anorg. Allg. Chem. 2018, 644, 989-992.

(special issue to commemorate the 60th birthday of Prof. A. Filippou)Link
225.

R. Thim, H. M. Dietrich, M. Bonath, D. Schädle, C. Maichle-Mössmer, and R. Anwander

Pentamethylcyclopentadienyl-Supported Rare-Earth-Metal Benzyl, Amide, and Imide Complexes

Organometalllics 2018, 37, 2769–2777.Link

224.

C. Stuhl and R. Anwander

Dimethylmagnesium Revisited

Dalton Trans. 2018, 47, 12546–12552.

(Themed Issue: Organometallic and Coordination Chemistry of the s-Block Metals)Link

223.

R. Thim, C. Maichle-Mössmer, and R. Anwander

Four-Membered Lutetaheterocycles

Organometalllics 2018, 37, 2563–2570.Link

222.

B. M. Wolf, C. Stuhl, and R. Anwander

Synthesis of homometallic divalent lanthanide organoimides from benzyl complexes

Chem. Commun. 2018, 54, 8826–8829.Link

221.

J. Friedrich, J. Qiao, C. Maichle-Mössmer, E. S. Schelter, and R. Anwander

Redox-enhanced hemilability of the tris(tert-butoxy)siloxy ligand at cerium

Dalton Trans. 2018, 47, 10113–10123Link

220.

A. M. Bienfait, B. M. Wolf, K. W. Törnroos, and R. Anwander
Trivalent Rare-Earth-Metal Bis(trimethylsilyl)amide Halide Complexes by Targeted Oxidations
Inorg. Chem. 2018, 57, 5204–5212.Link

219.

D. Werner, U. Bayer, N. E. Rad, G. B. Deacon, P. C. Junk, and R. Anwander
Unique and contrasting structures of homoleptic lanthanum and cerium 3,5-dimethylpyrazolates
Dalton Trans. 2018, 47, 5952–5955.Link

218.

L. Luo, Y. Liang, E. Sev. Erichsen, and R. Anwander
Hierarchical Mesoporous Organosilica/Silica Core-Shell Nanoparticles Capable of Controlled Fungicide Release
Chem. Eur. J. 2018, 24, 7200–7209.Link

217.

E. Le Roux, Y. Liang, and R. Anwander
Silica-Grafted Neodymium Catalysts for the Production of Ultra-High Molecular Weight cis-1,4-Polyisoprene
ChemCatChem 2018, 10, 1905–1911.
(special issue: Suported Molecular Catalysts)Link

216.

C. O. Hollfelder, L. N. Jende, D. Diether, T. Zelger, R. Stauder, C. Maichle-Mössmer, and R. Anwander

1,3-Diene Polymerization Mediated by Homoleptic Tetramethylaluminates of the Rare-Earth Metals

Catalysts 2018, 8, 61.
(special issue: Catalysts for the Controlled Polymerization of Conjugated Dienes)Link

215.

B. M. Wolf, C. Stuhl, C. Maichle-Mössmer, and R. Anwander

Dimethylcalcium

J. Am. Chem. Soc. 2018, 140, 2373–2383.Link

214.

L. N. Jende, C. Maichle-Mössmer, and R. Anwander

Rare-Earth Metal Formamidinate Complexes from [(C5Me5)LnMe2]3 and [LnMe3]n Precursors

J. Organomet. Chem. 2018, 857, 138–144.

(special issue to commemorate the 70th birthday of Prof. W. J. Evans)Link

213.

J. Friedrich, C. Maichle-Mössmer, and R. Anwander

Synthesis and derivatisation of ceric tris(tert-butoxy)siloxides

Chem. Commun. 2017, 53, 12044–12047.Link

212.

D. Diether, K. Tyulyunov, C. Maichle-Mössmer, and R. Anwander

Fluorenyl Half-Sandwich Bis(tetramethylaluminate) Complexes of the Rare-Earth Metals: Synthesis, Structure and Isoprene Polymerization

Organometallics 2017, 36, 4649–4659.

(Themed Issue on Organometallic Actinide and Lanthanide Chemistry)Link

211.

M. Bonath, C. O. Hollfelder, D. Schädle, C. Maichle-Mössmer, P. Sirsch, and R. Anwander

CH Bond Activation and Isoprene Polymerization by Lutetium Alkylaluminate/gallate Complexes Bearing a Peripheral Boryl and a Bulky Hydrotris(pyrazolyl)borate Ligand

Eur. J. Inorg. Chem. 2017, 4683–4692.

(themed issue: Boron Chemistry – A Rapidly Expanding Research Field)Link

210.

R. Anwander, M. Dolg, and F. T. Edelmann:

The difficult search for organocerium(IV) compounds

Chem. Soc. Rev. 2017, 46, 6697–6709.Link

209.

D. Werner, G. B. Deacon, P. C. Junk, and R. Anwander

Facile Reversible Benzophenone Insertion into Rare-Earth Metal Pyrazolate Complexes

Eur. J. Inorg. Chem. 2017, 3419–3428.Link

208.

J. Friedrich, D. Schneider, C. Maichle-Mössmer, and R. Anwander

Cerium(IV) Neopentoxide Complexes

Inorg. Chem. 2017, 56, 8114–8127.Link

207.

D. Schneider, N. Harmgarth, F. T. Edelmann, and R. Anwander

Ceric Cyclopentadienides Bearing Alkoxy, Aryloxy, Chlorido, or Iodido Co-Ligands

Chem. Eur. J. 2017, 23, 12243-12252.Link

206.

C. Lorenz, A.-J. Wicht, L. Guluzada, L. Luo, L. Jäger, B. Crone, U. Karst, R. Triebskorn, Y. Liang, R. Anwander, S. B. Haderlein, C. Huhn, H.-R. Köhler:

Nano-sized Al2O3 reduces acute toxic effects of thiacloprid on the non-biting midge Chironomus riparius

PlOS One 2017, 12, e0176356.Link

205.

D. Werner, G. B. Deacon, P. C. Junk, and R. Anwander

Pyrazolates advance cerium chemistry: a CeIII/CeIV redox equilibrium with benzoquinone

Dalton Trans. 2017, 46, 6265–6277.Link

204.

D. Schneider and R. Anwander

Pentamethylcyclopentadienyl-supported Cerocene(III) Complexes

Eur. J. Inorg. Chem. 2017, 1180–1188.Link

203.

L. Luo, Y. Liang, E. Sev. Erichsen, and R. Anwander

Monodisperse Mesoporous Silica Nanoparticles of Distinct Topology

J. Colloid Interf. Sci. 2017, 495, 84–93.Link

202.

A. M. Bienfait, B. M. Wolf, K. W. Törnroos, and R. Anwander

Donor-Solvent Dependent Cluster Formation of (C5Me5)SmI2(THF)x-type Half-Sandwich Complexes

Organometallics 2016, 35, 3743–3750.Link

201.

T. Spallek and R. Anwander

Rare-Earth Metal Diisopropylamide-Catalyzed Intramolecular Hydroamination

Dalton Trans. 2016, 45, 16393–16403.Link

200.

B. M. Wolf, C. Maichle-Mössmer, and R. Anwander

Synthesis and Reactivity of Discrete Calcium Imides

Angew. Chem. 2016, 128, 14097–14101; Angew. Chem. Int. Ed. 2016, 55, 13893–13897.Link

199.

T. Spallek, O. Heß, M. Meermann-Zimmermann, C. Meermann, M. G. Klimpel, F. Estler, D. Schneider, W. Scherer, M. Tafipolsky, K. W. Törnroos, C. Maichle-Mössmer, P. Sirsch and R. Anwander

Synthesis and structural diversity of rare-earth metal diisopropylamide complexes

Dalton Trans. 2016, 45, 13750–13765.Link

198.

N. Dettenrieder, H. M. Dietrich, C. Maichle-Mössmer, and R. Anwander

Yttrium Siloxide Complexes Bearing Terminal Methyl Ligands: Molecular Models for Ln-CH3 Terminated Silica Surfaces

Chem. Eur. J. 2016, 22, 13189–13200.Link

197.

A. M. Bienfait, B. M. Wolf, K. W. Törnroos, and R. Anwander
Ln(II)/Pb(II)–Ln(III)/Pb(0) Redox Approach toward Rare-Earth Metal Half-Sandwich Complexes
Organometallics 2015, 34(24), 5734-5744. Link

196.

D. Schädle, C. Maichle-Mössmer, K. W. Törnroos, and R. Anwander
Holmium(III) Supermesityl-Imide Complexes Bearing Methylaluminato/gallato Ligands
Inorganics 2015, 3, 500–510. Link

(themed issue: Rare-Earth Metal and Actinide Complexes)

195.

E. Le Roux, A. De Mallman, N. Merle, M. Taoufik, and R. Anwander
Immobilization of Heteroleptic Bis(oxazoline) Zinc Catalysts onto SBA-15 for Asymmetric Hydrosilylation
Organometallics 2015, 44, 5146–5154. Link

194.

D. Schädle, C. Schädle, C. Maichle-Mössmer, and R. Anwander
Rare-earth metal methylidene complexes with Ln32-CH2)(μ3-Me)(μ2-Me)3 core structure
Dalton Trans. 2015, 44, 18101–18110. Link

193.

N. Yuan, Y. Liang, E. Sev. Erichsen, and R. Anwander
Lanthanide complex-incorporated periodic mesoporous organosilica nanospheres with tunable photoluminescence
RSC Advances 2015, 5, 83368–83376. Link

192.

D. Schädle, C. Schädle, D. Schneider, C. Maichle-Mössmer, and R. Anwander
Versatile Ln2(μ-NR)2-Imide Platforms for Ligand Exchange and Isoprene Polymerization
Organometallics 2015, 34, 4994–5008. Link

191.

N. Yuan, Y. Liang, E. Sev. Erichsen, and R. Anwander
Embedding lanthanide-functionalized polymers into hollow mesoporous silica spheres: a ship-in-a-bottle approach to luminescent hybrid materials
RSC Advances 2015, 5, 67077–67081. Link

190.

D. Schädle, M. Enders, C. Schädle, C. Maichle-Mössmer, K. W. Törnroos, and R. Anwander
Reactivity of halfsandwich rare-earth metal methylaluminates toward primary amines
New J. Chem. 2015, 39, 7640–7648. Link

(themed issue: organo-f-element chemistry, PACIFICHEM 2015)

189. C. Schädle, C. Maichle-Mössmer, K. W. Törnroos, and R. Anwander
Hydride Transfer Capability of Selected Alkylalanes
Organometallics 2015, 34, 2667-2675. Link
188. D. Schädle, M. Meermann-Zimmermann, C. Schädle, C. Maichle-Mössmer, R. Anwander
Rare-Earth Metal Complexes with Terminal Imido Ligands
Eur. J. Inorg. Chem. 2015, 1334-1339. Link

187.

L. N. Jende, C. O. Hollfelder, C. Maichle-Mössmer, and R. Anwander
Rare-Earth Metal Allyl Complexes Supported by the 2-(N,N-Dimethylaminoethyl)tetramethylcyclopentadienyl Ligand: Structural Characterization, Reactivity, and Isoprene Polymerization
Organometallics 2015, 34, 32-41. Link

186.

D. Schädle, C. Maichle-Mössmer, C. Schädle, R. Anwander
Rare-Earth-Metal Methyl, Amide, and Imide Complexes Supported by a Superbulky Scorpionate Ligand
Chem. Eur. J. 2015, 21, 662-670. Link

185.

S. N. König, C. Maichle-Mössmer, K. W. Törnroos, R. Anwander
Siloxide Complexes of Chromium(II), Manganese(II), and Cobalt(II) as well as Chromium(III) Incorporating Potassium(I)
Z. Naturf. 2014, 69b, 1375-1383. Link

(special issue to commemorate the 80th birthday of Prof. H. Schmidbaur)

184.

D. Schneider, T. Spallek, C. Maichle-Mössmer, K. W. Törnroos, R. Anwander
Cerium tetrakis(diisopropylamide): a useful precursor for cerium(IV) chemistry
Chem. Comm., 2014, 50, 14763-14766. Link
183. A. M. Bienfait, C. Schädle, C. Maichle-Mössmer, K. W. Törnroos, and R. Anwander
Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2
Dalton Trans. 2014, 43, 17324–17332. Link
182.

S. N. König, D. Schneider, C. Maichle-Mössmer, B. M. Day, R. A. Layfield, R. Anwander
Divalent Transition Metal Silylamide Ate Complexes
Eur. J. Inorg. Chem. 2014, 4302-4309. Link

181.

U. J. Williams, D. Schneider, W. L. Dorfner, P. J. Carroll, C. Maichle-Mössmer, R. Anwander, and E. J. Schelter
Synthesis and Characterization of Amide, Alkoxide, and Aryloxide Cerium(IV) Coordination Compounds
Dalton Trans. 2014, 43, 16197-16206. Link

180.

N. Dettenrieder, C. Schädle, C. Maichle-Mössmer, R. Anwander
Reactivity of Boryllithium with AlMe3, AlEt3, and GaMe3, including the Synthesis of a Lanthanum Heterogallate Complex
Dalton Trans. 2014, 43, 15760-15770. Link

179.

S. N. König, C. Schädle, C. Maichle-Mössmer, R. Anwander
Silylamide Complexes of Chromium(II), Manganese(II), and Cobalt(II) Bearing the Ligands N(SiHMe2)2 and N(SiPhMe2)2
Inorg. Chem. 2014, 53, 4585–4597. Link
178. N. Dettenrieder, Y. Aramaki, B. M. Wolf, C. Maichle-Mössmer, X. Zhao, M. Yamashita, K. Nozaki, R. Anwander
Assessing the Brønsted Basicity of Diaminoboryl Anions: Reactivity toward Methylated Benzenes and Dihydrogen
Angew. Chem. 2014, 126, 6373–6377; Angew. Chem. Int. Ed. 2014, 53, 6259–6262. Link
177. N. Dettenrieder, C. O Hollfelder, L. N. Jende, C. Maichle-Mössmer, R. Anwander
Half-Sandwich Rare-Earth Metal Alkylaluminate Complexes Bearing Peripheral Boryl Ligands
Organometallics 2014, 33, 1528–1531. Link
176. D. Werner, G. B. Deacon, P. C. Junk, R. Anwander
Cerium(III/IV) Formamidinate Chemistry, and a Stable Cerium(IV) Diolate
Chem. Eur J. 2014, 20, 4426–4438. Link

175.

H. Skår, A. M. Bienfait, M. Schnitzlbaumer, K. W. Törnroos, and R. Anwander
High 1H Relaxivity Gadolinium Grafted Mesoporous Silica Materials,
Z. Anorg. Allg. Chem. 2014, 640, 604–615. Link

(themed issue: Silica-Based Nanoporous/Nanostructured Materials)

174. Y. Liang, E. Sev. Erichsen, and R. Anwander
Cobalt Hydroquinolate-modified Periodic Mesoporous Silicas
Microporous Mesoporous Mater. 2014,190, 316–323. Link
173. N. Dettenrieder, C. Schädle, C. Maichle-Mössmer, P. Sirsch, and R. Anwander
A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound
J. Am. Chem. Soc. 2014, 136, 886–889. Link
172. S. N. König, N. F. Chilton, C. Maichle-Mössmer, E. M. Pineda, T. Pugh, R. Anwander, and R. A. Layfield
Fast magnetic relaxation in an octahedral dysprosium tetramethyl-aluminate complex
Dalton Trans. 2014, 43, 3035–3038. Link
171. S. N. König, G. Gerstberger, C. Schädle, E. Herdtweck, and R. Anwander
Unusual Reaction Pathways of Gallium(III) Silylamide Complexes
Main Group Metal Chem. 2013, 36, 169-181. Link
170. C. Schädle, D. Schädle, K. Eichele, and R. Anwander
Methylaluminum-Supported Rare-Earth Metal Dihydrides
Angew. Chem. 2013, 125, 13480-13484; Angew. Chem. Int. Ed. 2013, 52, 13238-13242. Link
169. C. Schädle, A. Fischbach, E. Herdtweck, K. W. Törnroos, and R. Anwander
Reactivity of Yttrium Carboxylates toward Alkylaluminum Hydrides
Chem. Eur. J. 2013, 19, 16334-16341. Link
168. H. Skår, J. G. Seland, Y. Liang, N. Å. Frøystein, K. W. Törnroos, and R. Anwander
Screening the Relaxivity of Gadolinium Loaded Periodic Mesoporous Silica Functionalized via Soft Metalorganic Silylamide Grafting
Eur. J. Inorg. Chem. 2013, 5969-5979. Link
167. L. N. Jende, C. Maichle-Mössmer, and R. Anwander
Rare-Earth Metal Alkylaluminates supported by N-Donor Functionalized Cyclopentadienyl Ligands: C‒H Activation and Performance in Isoprene Polymerization
Chem. Eur. J. 2013, 19, 16321-16333. Link
166. Y. Liang and R. Anwander
Nanostructured catalysts via silylamide-based smart grafting
Dalton Trans. 2013, 42, 12521–12545. Link

165.

L. N. Jende, C. Maichle-Mössmer, C. Schädle, and R. Anwander
Yttrium Halfsandwich Complexes Bearing the 2-(N,N Dimethylaminoethyl)tetramethyl-cyclopentadienyl Ligand
J. Organomet. Chem. 2013, 744, 74–81. Link

(themed issue: applied organometallic chemistry, to commemorate the 65th birthday of Prof. W. A. Herrmann)

164. C. Schädle and R. Anwander
Rare-earth Metal-Promoted Hydroalumination
Eur. J. Inorg. Chem. 2013, 3302–3306. Link
163. H. Skår, Y. Liang, E. Sev. Erichsen, R. Anwander, and J. G. Seland
Relaxometric Properties of Gadolinium-grafted Mesoporous SBA-15 Silica Materials with Varying Pore Diameter
Microporous Mesoporous Mat. 2013, 175, 125-133. Link
162. Y. Liang, E. Sev. Erichsen, and R. Anwander
Functionalization of large-pore periodic mesoporous silicas: metal silylamide and isopropoxide molecular grafting and secondary surface ligand exchange
Dalton Trans. 2013, 42, 6922-9635. Link
161. S. Hamidi, L. N. Jende, H. M. Dietrich, D. Werner, C. Maichle-Mössmer, K. W. Törnroos, G. B. Deacon, P. C. Junk, R. Anwander
Organoaluminum and -gallium Formamidinate Complexes
Eur. J. Inorg. Chem. 2013, 2460-2466. Link

160.

A. R. Crozier, C. Schädle, C. Maichle-Mössmer, K. W. Törnroos, and R. Anwander
Synthesis and grafting of CAN-derived tetravalent cerium alkoxide silylamide precursors onto mesoporous silica MCM-41
Dalton Trans. 2013, 42, 5491–5499. Link

159.

S. Hamidi, L. N. Jende, H. M. Dietrich, C. Maichle-Mössmer, K. W. Törnroos, G. B. Deacon, P. C. Junk, R. Anwander
C–H Bond Activation and Isoprene Polymerization by Rare-Earth Metal Tetramethylaluminate Complexes Bearing Formamidinato N-Ancillary Ligands
Organometallics 2013, 32, 1209-1223. Link

(themed issue: Recent Advances in Organo-f-Element Chemistry)

158.

H. Kaneko, H. M. Dietrich, C. Schädle, H. Tsurugi, K. Mashima, K. W. Törnroos, and R. Anwander
Synthesis of Rare-Earth Metal Iminopyrrolyl Complexes from Alkyl Precursors: Ln→Al N-Ligand Transfer
Organometallics 2013, 32, 1199-1208. Link
157. A. R. Crozier, K. W. Törnroos, C. Maichle-Mössmer, and R. Anwander
Trivalent Cerium and Praseodymium Aromatic Ketone Adducts
Eur J. Inorg. Chem. 2013, 409-414. Link
156. A. R. Crozier, A. M. Bienfait, C. Maichle-Mössmer, K. W. Törnroos, and R. Anwander
A homolpetic tetravalent cerium silylamide
Chem. Commun. 2013, 49, 87–89. Link
155. Y. Liang, E. S. Erichsen, C. Song, and R. Anwander
Organozinc- and Imidazole-Modified Periodic Mesoporous Organosilicas via Molecular Grafting
Eur. J. Inorg. Chem. 2012, 5741–5751. Link

154.

E. Le Roux, Y. Liang, F. Nief, and R. Anwander
Heterogenization of Lanthanum and Neodymium Mono-phosphacyclopentadienyl Bis(tetramethylaluminate) Complexes onto Periodic Mesoporous Silica SBA-15
Organometallics 2012, 31, 6526–6537. Link

153.

D. Schädle, C. Schädle, K. W. Törnroos, and R. Anwander
Organoaluminum-assisted Formation of Rare-Earth Metal Imide Complexes
Organometallics 2012, 31, 5101–5107. Link
152. T. Deschner, M. Klimpel, M. Tafipolsky, W. Scherer, K. W. Törnroos, and R. Anwander
Postfunctionalization of Periodic Mesoporous Silica SBA-1 with Magnesium and Iron(II) Silylamides
Dalton Trans. 2012, 41, 7319-7326. Link
151. T. K. Panda, H. Kaneko, O. Michel, K. Pal, H. Tsurugi, K. W. Törnroos, R. Anwander, and K. Mashima
Dianion and Monoanion Ligation of 1,4-Diaza-1,3-butadiene to Barium, Strontium, and Calcium
Organometallics 2012, 31, 3178–3184. Link
150. O. Michel, H. M. Dietrich, R. Litlabø K. W. Törnroos, C. Maichle-Mössmer, and R. Anwander
Tris(pyrazolyl)borate Complexes of the Alkaline-Earth Metals: Alkylaluminate Precursors and Schlenk-type Rearrangements
Organometallics 2012, 31, 3119–3127. Link
149. N. Dettenrieder, H. M. Dietrich, C. Schädle, C. Maichle-Mössmer, K. W.Törnroos, and R. Anwander
Organoaluminum Boryl Complexes
Angew. Chem. 2012, 124, 4537–4541; Angew. Chem. Int. Ed. 2012, 51, 4461–4465. Link

148.

O. Michel, H. Kaneko, H. Tsurugi, K. Yamamoto, K. W. Törnroos, R. Anwander, and K. Mashima
Diene Dissolution of the Heavier Alkaline-Eath Metals
Eur. J. Inorg. Chem. 2012, 18, 998–1003. Link
147. J. A. Gladysz and R. Anwander
Inaugural Schlenk Lecture at the University of Tübingen
Organometallics 2012, 31, 773–774. Link
146. O. Michel, K. W. Törnroos, C. Maichle-Mössmer and R. Anwander
Barium Bis(dimethylsilyl)amide: Adduct vs. Oxo Formation
Eur. J. Inorg. Chem. 2012, 18, 44–47. Link
145. R. Anwander
Schlenk in Tübingen
Nachr. Chem. 2011, 59, 951–953. Link
144. H. M. Dietrich, K. W. Törnroos, and R. Anwander
LaAl3Et12: A Homoleptic Ethyllanthanum Complex
Angew. Chem. 2011, 123, 12295–12299; Angew. Chem. Int. Ed. 2011, 50, 12089–12093. Link
143. O. Michel, S. König, K. W. Törnroos, C. Maichle-Mössmer and R. Anwander
Surface Organobarium and –Magnesium Chemistry on Periodic Mesoporous Silica MCM-41: Convergent and Sequential Approaches Traced by Molecular Models
Chem. Eur. J. 2011, 17, 11857–11867. Link
142. O. Michel, K. Yamamoto, H. Tsurugi, K. W. Törnroos, C. Maichle-Mössmer, K. Mashima, and R. Anwander
Reactivity of Permethylated Magnesium Complexes Toward ß-Diimines
Organometallics 2011, 30, 3818–3825. Link
141. T. Deschner, K. W. Törnroos, and R. Anwander
Iron Silylamide-Grafted Periodic Mesoporous Silica
Inorg. Chem. 2011, 50, 7217–7228. Link
140. G. Occhipinti, C. Meermann, H. M. Dietrich, R. Litlabø, F. Auras, K. W. Törnroos, C. Maichle-Mössmer, V. R. Jensen, and R. Anwander
Synthesis and Stability of Homoleptic Metal(III) Tetramethylaluminates
J. Am. Chem. Soc. 2011, 133, 6323-6337. Link
139. T. Deschner, B.-T. Lønstad, M. Widenmeyer, and R. Anwander
Functionalization of MCM-41 and SBA-1 with Titanium(IV) (Silyl)Amides
J. Mater. Chem. 2011, 21, 5620-5628. Link
138. O. Michel, K. W. Törnroos, C. Maichle-Mössmer, and R. Anwander
Peralkylated Barium Complexes
Chem. Eur. J. 2011, 17, 4964-4967. Link
137. T. Deschner, Y. Liang, and R. Anwander
Silylation Efficiency of Chlorosilanes, Alkoxysilanes, and Monosilazanes on Periodic Mesoporous Silica
J. Phys. Chem. C 2010, 114, 22603-22609. Link
136. E. Le Roux, Y. Liang, M. P. Storz, and R. Anwander
Intramolecular Hydroamination/Cyclization of Aminoalkenes Catalyzed by Ln[N(SiMe3)2]3 Grafted onto Periodic Mesoporous Silicas
J. Am. Chem. Soc. 2010, 132, 16368-16371. Link
135. P. Dröse, A. R. Crozier, S. Lashkari, J. Gottfriedsen, S. Blaurock, C. G. Hrib, C. Maichle-Mössmer, C. Schädle, R. Anwander, and F. T. Edelmann:
Facile Access to Tetravalent Cerium Compounds: One-Electron Oxidation using Iodine(III) Reagents
J. Am. Chem. Soc. 2010, 132, 14046-14047. Link
134. M. Zimmermann and R. Anwander
Homoleptic Rare-Earth Metal Complexes Containing Ln-C σ-Bonds
Chem. Rev. 2010, 110, 6194-6259. Link
133. E. Le Roux, O. Michel, H.-M. Sommerfeld, Y. Liang, C. Maichle-Mössmer, K. W. Törnroos, and R. Anwander
Grafting of peralkylated Ln(II)Al(III) heterobimetallic complexes onto periodic mesoporous silica KIT-6
Dalton Trans. 2010, 39, 8552-8559. Link
(themed issue: bridging the gap in catalysis via multidisciplinary approaches)
132. R. Litlabø, M. Enders, K. W. Törnroos, and R. Anwander
Bis(Tetramethylaluminate) complexes of Yttrium and Lanthanum Supported by a Quinolyl-Substituted Cyclopentadienyl Ligand: Synthesis and Performance in Isoprene Polymerization
Organometallics 2010, 29, 2588-2595. Link
131. M. Zimmermann, D. Rauschmaier, K. Eichele, K. W. Törnroos, and R. Anwander
Amido-Stabilized Rare-Earth Metal Mixed Methyl Methylidene Complexes
Chem. Commun. 2010, 46, 5346-5348. Link

130.

H. M. Dietrich, K. W. Törnroos, E. Herdtweck, and R. Anwander
Donor-assisted tetramethylaluminate/gallate exchange in organolanthanide complexes: pushing the limits of Pearson´s HSAB concept
Dalton Trans. 2010, 39, 5783-5785. Link

129. M. Zimmermann, J. Volbeda, K. W. Törnroos, and R. Anwander
Tetramethylcyclopentadienyl-Supported Rare-Earth Metal Bis(tetramethyl)aluminate Complexes: Synthesis, Structural Chemistry, Cation Formation, and Isoprene Polymerization
Comptes Rendus Chimie 2010, 13, 651-660. Link
(themed issue: Chemistry of the f-Elements)
128. C. Schädle, C. Meermann, K. W. Törnroos, and R. Anwander
Rare-Earth Metal Phenyl(trimethylsilyl)amide Complexes
Eur. J. Inorg. Chem. 2010, 2841-2852. Link
(themed issue: Chemistry of the f-Elements)
127. R. Litlabø, H. S. Lee, M. Niemeyer, K. W. Törnroos, and R. Anwander
Rare-Earth Metal Bis(tetramethylaluminate) Complexes Supported by a Sterically Crowded Triazenido Ligand
Dalton Trans. 2010, 39, 6815-6825. Link
(themed issue: new horizons in organo-f-element chemistry)
126. R. Anwander
Buchrezension:  Metal Amide Chemistry
Angew. Chem 2010, 122, 855-856; Angew. Chem. Int. Ed. 2010, 49, 843. Link
125. M. Zimmermann, R. Litlabø, K. W. Törnroos, and R. Anwander Metastable Lu(GaMe4)3 Reacts Like Masked [LuMe3]: Synthesis of an Unsolvated Lanthanide Dimethyl Complex
Organometallics 2009, 28, 6646-6649. Link
124. Y. Liang, E. S. Erichsen, M. Hanzlik, and R. Anwander
Ethylene-bridged Mesoporous Organosilicas with Hexagonal and Cubic Symmetry
Z. Naturforsch. 2009, 64b, 1289-1304.
(special issue to commemorate the 75th birthday of Prof. H. Schmidbaur)
123. R. Litlabø, K. Saliu, M. J. Ferguson, R. McDonald, J. Takats, and R. Anwander
Monomeric Tetraalkylaluminates of Divalent Ytterbium Stabilized by a Bulky Tris(pyrazolyl)borato Ligand
Organometallics 2009, 28, 6750-6754. Link
122. H. M. Dietrich, K. W. Törnroos, E. Herdtweck, and R. Anwander
Tetramethylaluminate and Tetramethylgallate Coordination in Rare-Earth Metal Halfsandwich and Metallocene Complexes
Organometallics 2009, 28, 6739-6749. Link
121. O. Michel, C. Meermann, K. W. Törnroos, and R. Anwander
Alkaline-Earth Metal Alkylaluminate Chemistry Revisited
Organometallics 2009, 28, 4783-4790. Link
120. E. Le Roux and R. Anwander
Surface Organolanthanide and -Actanide Chemistry
Modern Surface Organometallic Chemistry
(Eds.: J.-M. Basset, R. Psaro, D. Roberto, R. Ugo),
VCH Verlagsgesellschaft mbH, Weinheim, 2009, 455-512. Link
119. C. Meermann, K. W. Törnroos, and R. Anwander
Scandium SALEN Complexes Bearing Chloro, Aryloxo, and Hydroxo Ligands
Inorg. Chem. 2009, 48, 2561–2570. Link
118. H. M. Dietrich, J. W. Ziller, R. Anwander, and J. W. Evans
Reactivity of (C5Me5)2UMe2 and (C5Me5)2UMeCl Toward Group 13 Alkyls
Organometallics 2009, 28, 1173–1179. Link
117. C. Meermann, K. Ohno, K. W. Törnroos, K. Mashima, and R. Anwander
Rare-Earth Metal Bis(dimethylsilyl)amide Complexes Supported by Cyclooctatetraenyl Ligand
Eur. J. Inorg. Chem. 2009, 76–85. Link
116. R. Litlabø, M. Zimmermann, K. Saliu, J. Takats, K. W. Törnroos, and R. Anwander
A Rare-Earth Metal Variant of the Tebbe Reagent
Angew. Chem. 2008, 120, 9702–9706; Angew. Chem. Int. Ed. 2008, 47, 9560–9564. Link
115. Q. Liu, C. Meermann, H. W. Görlitzer, O. Runte, E. Herdtweck, P. Sirsch, K. W. Törnroos, and R. Anwander
Cationic rare-earth metal SALEN complexes
Dalton Trans. 2008, 6170–6178. Link
114. L. C. H. Gerber, E. Le Roux, K. W. Törnroos, and R. Anwander
Elusive Trimethyllanthanum: Snapshots of Extensive Methyl Group Degradation in La– Al Heterobimetallic Complexes
Chem. Eur. J. 2008, 14, 9555–9564. Link
113. M. Zimmermann, K. W. Törnroos, R. M. Waymouth, and R. Anwander
Structure-Reactivity Relationships Amido-Pyridine-Supported Rare-Earth Metal Alkyl Complexes
Organometallics 2008, 27, 4310–4317. Link
112. M. Zimmermann, K. W. Törnroos, H. Sitzmann, and R. Anwander
Half-Sandwich Bis(tetramethylaluminate) Complexes of the Rare-Earth Metals: Synthesis, Structural Chemistry, and Performance in Isoprene Polymerization
Chem. Eur. J. 2008, 14, 7266–7277. Link
111. H.-M. Sommerfeldt, C. Meermann, K. W. Törnroos, and R. Anwander
Distinct Reaction Pathways of Peralkylated LnIIAlIII Heterobimetallic Complexes with Substituted Phenols
Inorg. Chem. 2008, 47, 4696–4705. Link
110. C. Meermann, G. Gerstberger, M. Spiegler, K. W. Törnroos, and R. Anwander
Donor and Ate Coordination in Rare-Earth Metal Bis(dimethylsilyl)amide Complexes
Eur. J. Inorg. Chem. 2008, 2014–2023. Link
109. R. Anwander
Immobilization of Molecular Catalysts
in Handbook of Heterogeneous Catalysis (Eds.: G. Ertl, H. Knözinger, F. Schüth and J. Weitkamp), 2nd edition, VCH Verlagsgesellschaft mbH, Weinheim, 2008, Volume 1, pp. 583-613.

108.

H.-M. Sommerfeldt, C. Meermann, M. G. Schrems, K. W. Törnroos, N. A. Frøystein, R. J. Miller, E.-W. Scheidt, W. Scherer, and R. Anwander
Characterization and reactivity of peralkylated LnIIAlIII heterobimetallic complexes
Dalton Trans. 2008, 1899-1907. Link
107. M. Zimmermann, J. Takats, G. Kiel, K. W. Törnroos, and R. Anwander
Ln(III) Methyl and Methylidene Complexes Stabilized by a Bulky Hydrotris(pyrazolyl)borate Ligand
Chem. Commun. 2008, 612–614. Link
106. Y. Liang, E. S. Erichsen, M. Hanzlik, and R. Anwander
Facile Mesophase Control of Periodic Mesoporous Organosilicas under Basic Conditions
Chem. Mater. 2008, 20, 1451-1458. Link
105. M. Zimmermann, K. W. Törnroos, and R. Anwander
Cationic Rare-Earth Metal Complexes for the Living trans-1,4 Isoprene Polymerization
Angew. Chem. 2008, 120, 787–790; Angew. Chem. Int. Ed. 2008, 47, 775–778. Link

104.

M. Zimmermann, F. Estler, E. Herdtweck, K. W. Törnroos, and R. Anwander
Distinct C–H Bond Activation Pathways in Diamido-Pyridine-Supported Rare-Earth Metal Hydrocarbyl Complexes
Organometallics 2007, 26, 6029–6041. Link
103. E. Le Roux, F. Nief, F. Jaroschik, K. W. Törnroos, and R. Anwander
Mono-Phosphacyclopentadienyl Bis(tetramethylaluminate) Lanthanide Complexes
Dalton Trans. 2007, 4866-4870. Link

102.

M. Zimmermann, N. A. Frøystein, A. Fischbach, P. Sirsch, H. M. Dietrich, K. W. Törnroos, E. Herdtweck, and R. Anwander
Homoleptic Tetramethylaluminate Complexes of the Rare-Earth Metals: Structural Chemistry, Reactivity, and Performance in Isoprene Polymerization
Chem. Eur. J. 2007, 13, 8784-8800. Link

101.

C. Meermann, K. W. Törnroos, W. Nerdal, and R. Anwander
Rare-Earth Metal Mixed Chloro/Methyl Compounds: Heterogeneous–Homogeneous Borderline Catalysts in 1,3-Diene Polymerization
Angew. Chem. 2007, 119, 6628–6633; Angew. Chem. Int. Ed. 2007, 46, 6508–6513. Link
100. C. Zapilko, Y. Liang, and R. Anwander
Size Selective SOMC on Cagelike Mesoporous Silicas
Chem. Mater. 2007, 19, 3171–3176. Link
99. Y. Liang and R. Anwander
Disilazane Silylation of Inorganic-organic Hybrid Periodic Mesoporous Organosilicas
J. Mater. Chem. 2007, 17, 2506–2516. Link
98. M. Zimmermann, K. W. Törnroos, and R. Anwander
Alkyl Migration and a New Tetramethylaluminate Coordination Mode: Unusual Reactivity of Organolanthanide Imino-Amido-Pyridine Complexes
Angew. Chem. 2007, 119, 3187–3191; Angew. Chem. Int. Ed. 2007, 46, 3126–3130. Link
97. C. Zapilko, Y. Liang, W. Nerdal, and R. Anwander
A General Strategy for the Rational Design of Size-Selective Mesoporous Catalysts
Chem. Eur. J. 2007, 3169-3176. Link
96. C. Zapilko, M. Widenmeyer, I. Nagl, F. Estler, R. Anwander, G. Raudaschl-Sieber, O. Groeger, and G. Engelhardt:
Advanced Surface Functionalization of Periodic Mesoporous Silica: Kinetic Control by Novel Silylamines
J. Am. Chem. Soc. 2006, 128, 16266–16276. Link
95. A. Fischbach, E. Herdtweck, and R. Anwander
Synthesis and Derivatization of Halflanthanidocene Aryl(Alk)oxide Complexes
Inorg. Chim. Acta 2006, 359, 4855–4864. Link
(special issue to commemorate protagonists of chemistry: Prof. W. A. Herrmann)
94. A. Fischbach, C. Meermann, G. Eickerling, W. Scherer, and R. Anwander
Discrete Lanthanide Aryl(alk)oxide Trimethylaluminum Adducts as Isoprene Polymerization Catalysts
Macromolecules 2006, 39, 6811-6816. Link
93. A. Fischbach and R. Anwander
Rare-Earth Metals and Aluminum Getting Close in Ziegler-type Organometallics
Adv. Polym. Sci. 2006, 204, 155-281. Link

92.

H. M. Dietrich, C. Meermann, K. W. Törnroos, and R. Anwander
Sounding out the Reactivity of Trimethylyttrium
Organometallics 2006, 25, 4316-4321. Link
91. H. M. Dietrich, K. W. Törnroos, and R. Anwander
Ionic Carbenes: Synthesis, Structural Characterization, and Reactivity of Rare-Earth Metal Methylidene Complexes
J. Am. Chem. Soc. 2006, 128, 9298-9299. Link
90. H. M. Dietrich, O. Schuster, K. W. Törnroos, and R. Anwander
Heterobimetallic Halflanthanidocene Clusters: Novel Mixed Tetramethylaluminato Chloro Coordination
Angew. Chem. 2006, 118, 4977-4982; Angew. Chem. Int. Ed. 2006, 45, 4858-4863. Link
89. M. Zimmermann, K. W. Törnroos and R. Anwander
Implementation of Ln(AlMe4)3 as Precursors in Postlanthanidocene Chemistry
Organometallics 2006, 25, 3593-3598. Link
88. A. Fischbach, F. Perdih, P. Sirsch, W. Scherer, and R. Anwander
Structure-Reactivity Relationships in Rare-Earth Metal Carboxylate-based Binary Ziegler-type Catalysts
Organometallics 2006, 25, 1626-1642. Link
87. Y. Liang and R. Anwander
Surface organometallic chemistry on periodic mesoporous organosilica: Generation of surface-confined zinc and yttrium species
Dalton Trans. 2006, 1909-1918. Link
86. C. Zapilko and R. Anwander
Size-Selective Surface Silylation of Cage-like Mesoporous Silica SBA-2 with Disilazane Reagents
Chem. Mater. 2006, 18, 1479-1482. Link
85. H. M. Dietrich, H. Grove, K. W. Törnroos, and R. Anwander
Multiple C–H Bond Activation in Group 3 chemistry: Synthesis and Structural Characterization of an Yttrium–Aluminum–Methine Cluster
J. Am. Chem. Soc. 2006, 128, 1458-1459. Link
84. Y. Liang, M. Hanzlik, and R. Anwander
Periodic Mesoporous Ethylenesilicas: Mesophase Control via Binary Cationic Surfactant Mixtures
J. Mater. Chem. 2006, 16, 1238-1253. Link
83. C. Meermann, P. Sirsch, K. W. Törnroos and R. Anwander
Synthesis and structural characterization of scandium SALEN complexes
Dalton Trans. 2006, 1041-1050. Link
82. M. G. Schrems, H. M. Dietrich, K. W. Törnroos and R. Anwander
[LnIIAlIII2(alkyl)8]x: donor addition instead of donor-induced cleavage
Chem. Commun. 2005, 5922-5924. Link
81. H. M. Dietrich, C. Zapilko, E. Herdtweck, and R. Anwander
Ln(AlMe4)3 as New Synthetic Precursors in Organolanthanide Chemistry: Efficient Access to Half-Sandwich Hydrocarbyl Complexes
Organometallics 2005, 24, 5767-5771. Link
80. C. Zapilko and R. Anwander
Grafting of Magnesium and Yttrium Silylamides onto Periodic Mesoporous Silica SBA-1
Stud. Surf. Sci. Catal. 2005, 158, 461-468. Link
79. Y. Liang, M. Hanzlik and R. Anwander
Ethylene-bridged periodic mesoporous organosilicas with Fm3m symmetry
J. Mater. Chem. 2005, 15, 3919-3928. Link
78. H. M. Dietrich, G. Raudaschl-Sieber, and R. Anwander
Trimethylyttrium and Trimethyllutetium
Angew. Chem. 2005, 117, 5437-5440; Angew. Chem. Int. Ed. 2005, 44, 5303-5306. Link
77. Y. Liang, M. Hanzlik and R. Anwander
PMO[KIT-5]-n: Synthesis of highly ordered three-dimensional periodic mesoporous organosilicas with Fm3m symmetry
Chem. Commun. 2005, 525-527. Link
76.

A. Fischbach, G. Eickerling, W. Scherer, E. Herdtweck, and R. Anwander
Synthesis and Derivatization of Homoleptic Dinuclear Lanthanide Siloxide Complexes
Z. Naturforsch. 2004, 59b, 1353-1364. in press
(special issue to commemorate the 70th birthday of Prof. H. Schmidbaur)

75. Y. Liang and R. Anwander
Synthesis of Pore-enlarged Organosilicas under Basic Conditions
Microporous Mesoporous Mater. 2004, 72, 153-165. Link
74. A. Fischbach, M. G. Klimpel, M. Widenmeyer, E. Herdtweck, W. Scherer and R. Anwander,
Stereospecific Polymerization of Isoprene with Molecular and MCM-48-grafted Lanthanide(III)-Tetraalkylaluminates LnAl3R12
Angew. Chem. 2004, 116, 2284-2289; Angew. Chem. Int. Ed. 2004, 43, 2234-2239. Link
73. R. Anwander, I. Nagl, C. Zapilko, and M. Widenmeyer
Methyl Methacrylate Polymerization at Samarium(II)-Grafted MCM-41
Tetrahedron 2003, 59, 10567-10574. Link
(symposium-in-print: recent advances in rare earth chemistry)
72.

 
R. Anwander, M. G. Klimpel, H. M. Dietrich, D. J. Shorokhov and W. Scherer
High Tetraalkylaluminate Fluxionality in Half-Sandwich Complexes of the Trivalent Rare-Earth Metals
Chem. Commun. 2003, 1008-1009. Link
71.

R. Anwander

Corey´s reagent, Early-late heterobimetallic complexes, Immortal polymerization, Itsuno´s reagent, Lanthanidocenes, Living polymerization, Mosher´s reagent, Phthalocyanine as a ligand, Sharpless´s reagent, Tied-back ligands
in Catalysis from A to Z (Eds.: B. Cornils, W. A. Herrmann, W. Schlögl, and C.-H. Wong),
VCH, Weinheim, 2003, 2nd Ed., pp. 8, 44, 104, 190, 253, 258, 341, 353, 360, 398, 419, 444, 449, 458, 513, 525, 597, 639, 672, 688, 694, 770.

70. F. Estler, E. Herdtweck, R. Anwander, G. Eickerling, and W. Scherer:
Organorare Earth Complexes Supported by Chelating Diamide Ligands
Organometallics 2003, 22, 1212-1222. Link
69. A. Fischbach, E. Herdtweck, R. Anwander, G. Eickerling, and W. Scherer
Reactivity of Trimethylaluminum with Lanthanide Aryloxides: Adduct and Tetramethylaluminate Formation
Organometallics 2003, 22, 499-509. Link
68. M. G. Klimpel, P. Sirsch, W. Scherer, and R. Anwander
DIBAH-Mediated Amide–Hydride Transformation in ansa-Lanthanidocene(III) Complexes
Angew. Chem. 2003, 115, 594-597; Angew. Chem. Int. Ed. 2003, 42, 574-577. Link
67. A. Fischbach, F. Perdih, P. Sirsch, W. Scherer, and R. Anwander
Rare-Earth Ziegler–Natta Catalysts: Carboxylate-Alkyl Interchange
Organometallics 2002, 21, 4569-4571. Link
66. R. Anwander, F. Estler, W. A. Herrmann, H. W. Görlitzer, W. Ude und E. Osthaus
Neue Scandium-Komplexe, Verfahren zu deren Herstellung sowie Verwendung
DE 102 42 471.3 v. 11.09.2002, Röhm GmbH&Co.KG, 64293 Darmstadt (DE).
65. M. G. Klimpel, J. Eppinger, P. Sirsch, W. Scherer, and R. Anwander
The Lanthanide Ziegler–Natta Model: Aluminum-Mediated Chain Transfer
Organometallics 2002, 21, 4021-4023. Link
64. F. Estler, E. Herdtweck and R. Anwander
O-benzylated calix[4]arenes as ancillary ligands in organolanthanide chemistry
J. Chem. Soc., Dalton Trans. 2002, 3088-3089. Link
63. R. Anwander
Nanostructured Rare Earth Catalysts via Advanced Surface Grafting
in Nanostructured Catalysts (Ed.: S. Scott), Kluwer Academic/Plenum Publishers, New York, 2002, pp. 17-56.
62. M. Widenmeyer and R. Anwander
Pore Size Control of Highly Ordered Mesoporous Silica MCM-48
Chem. Mater. 2002, 14, 1827-1831. Link
61.

R. Anwander

Buchrezension: Alkoxo and Aryloxo Derivatives of Metals
Angew. Chem. 2002, 114, 1881-1882; Angew. Chem. Int. Ed. 2002, 41, 1801-1803. Link

60. M. G. Klimpel, H. W. Görlitzer, M. Tafipolsky, W. Scherer, M. Spiegler, and R. Anwander
β(Si-H) agostic bonding in sterically crowded lanthanidocene silylamide complexes
J. Organomet. Chem. 2002, 647, 236-244. Link
(highlights of the international symposia on Group 3 and f element chemistry in Hawai (Pacifichem 2000) and Garching (Tage der Seltenen Erden 2001))
59. R. Anwander
Rare Earth Elements in Homogeneous Catalysis
in Applied Homogeneous Catalysis with Organometallic Compounds (Eds.: B. Cornils and W.A. Herrmann), 2nd edition,
VCH Verlagsgesellschaft mbH, Weinheim, 2002, pp. 974-1014.
58. R. Anwander, H. W. Görlitzer, W. A. Herrmann, K. Dorn, E. Osthaus und H. Schwind
Verfahren zur Herstellung von Polymerisaten und Copolymerisaten alpha-substituierter Acrylverbidnungen
DE 100 10 513 A1 v. 13.09.2001, Röhm GmbH&Co.KG, 64293 Darmstadt (DE).
57. R. Anwander, H. W. Görlitzer, W. A. Herrmann, K. Dorn, E. Osthaus und H. Schwind
Verfahren zur Seltenerdmetall-katalysierten Synthese von Polyacrylsäureestern mit hoher Isotaktizität
DE 100 10 511 A1 v. 13.09.2001, Röhm GmbH&Co.KG, 64293 Darmstadt (DE).
56. R. Anwander
SOMC@PMS. Surface Organometallic Chemistry at Periodic Mesoporous Silica
Chem. Mater. 2001, 13, 4419-4438. Link
55. M. G. Klimpel, R. Anwander, M. Tafipolsky, and W. Scherer
Peralkylated Ytterbium(II) Aluminate Complexes YbAl2R8. New Insights into the Nature of Aluminate Coordination
Organometallics 2001, 20, 3983-3992. Link
54. M. Widenmeyer, S. Grasser, K. Köhler, and R. Anwander
TiOx-overlayers on MCM-48 silica by consecutive grafting
Microporous Mesoporous Mater. 2001, 44-45, 327-336. Link
53. W. J. Evans, M. A. Johnston, R. D. Clark, R. Anwander, and J. W. Ziller
Heteroleptic and Heterometallic Divalent Lanthanide Bis(trimethylsilyl)-amide Complexes: Mixed Ligand, Inverse Sandwich, and Heterometallic Complexes
Polyhedron 2001, 20, 2483-2490. Link
52. I. Nagl, M. Widenmeyer, E. Herdtweck, G. Raudaschl-Sieber, and R. Anwander
Scandium Methyl Surface Species via SOMC on MCM-41 Silica
Microporous Mesoporous Mater. 2001, 44-45, 311-319. Link
51. G. Gerstberger and R. Anwander
Screening of MCM-41 grafted rare earth metal complexes for asymmetric catalysis
Microporous Mesoporous Mater. 2001, 44-45, 303-310. Link
50. W. Hieringer, J. Eppinger, R. Anwander, and W. A. Herrmann
C2-symmetric Ansa-Lanthanidocenes. Theoretical Evidence for a Symmetric b(Si-H) Diagostic Interaction
J. Am. Chem. Soc. 2000, 122, 11983-11994. Link
49. M. G. Klimpel, W. A. Herrmann, and R. Anwander
Fluxional Indenyl-Derived Ytterbocene(II) Complexes: The SiHR2 group as a NMR Spectroscopic Probe
Organometallics 2000, 19, 4666-4668. Link
48. R. Anwander, J. Eppinger, I. Nagl, W. Scherer, and M. Tafipolsky
Yttrium(III) Calix[4]arene Complexes - Silylation and Silylamine Elimination Reactions on Model Oxo Surfaces
Inorg. Chem. 2000, 39, 4713-4720. Link
47. R. Anwander, I. Nagl, M. Widenmeyer, G. Engelhardt, O. Groeger, C. Palm, and T. Röser
Surface Characterization and Derivatization of MCM-41 Silicas via Silazane Silylation
J. Phys. Chem. 2000, 104, 3532-3544. Link
46. J. Eppinger, M. Spiegler, W. Hieringer, W. A. Herrmann, and R. Anwander
C2-symmetric Ansa-Lanthanidocenes. Synthesis via Silylamine Elimination and b(Si-H) Agostic Rigidity
J. Am. Chem. Soc. 2000, 122, 3080-3096. Link
45. R. Anwander
Acid-base catalysis, Ancillary ligand, Brönsted acid-base concept, Electronic effects in homogeneous catalysis, Heteroleptic complexes, Homoleptic complexes, HSAB concept, Lewis acid-base concept, Model surfaces of supported catalysts, Rare earth metals as catalysts, Salen ligands, Ship-in-the-bottle catalysts
in Catalysis from A to Z (Eds.: B. Cornils, W. A. Herrmann, W. Schlögl, and C.-H. Wong),
VCH, Weinheim, 2000, pp. 6, 34, 74, 192-193, 256, 265, 271, 339, 384-385, 482, 509-510, 525-526.
44. I. Nagl, M. Widenmeyer, S. Grasser, K. Köhler, and R. Anwander
Surface-Confined Ketyl Radicals via Samarium(II)-Grafted Mesoporous Silica
J. Am. Chem. Soc. 2000, 122, 1544-1545. Link
43. H. W. Görlitzer, M. Spiegler and R. Anwander
C2-symmetric bis(oxazolinato) complexes of yttrium and lanthanum
J. Chem. Soc., Dalton Trans. 1999, 4287-4288. Link
42. R. Anwander, H. W. Görlitzer, G. Gerstberger, C. Palm, O. Runte and M. Spiegler
Grafting of bulky rare earth metal complexes onto mesoporous silicate MCM-41
J. Chem. Soc., Dalton Trans. 1999, 3611-3615. Link
41. I. Nagl, W. Scherer, M. Tafipolsky, and R. Anwander
The First Oligomeric Samarium(II) Silylamide: Coordinative Saturation via Agostic Sm...SiH Interactions
Eur. J. Inorg. Chem. 1999, 1405-1407. Link
40. G. Gerstberger, C. Palm, and R. Anwander
The Danishefsky Hetero Diels-Alder Reaction Mediated by Organolanthanide-Modified Mesoporous Silicate MCM-41
Chem. Eur. J. 1999, 5, 997-1005. Link
39. R. Anwander
Principles in Organolanthanide Chemistry
Top. Organomet. Chem. 1999, 2, 1-61. Link
38. R. Anwander, C. Palm, G. Gerstberger, O. Groeger and G. Engelhardt:
Enhanced catalytic activity of MCM-41 grafted aluminium isopropoxide in MPV reductions
Chem. Commun. 1998, 1811-1812. Link
37.

R. Anwander and C. Palm
Meerwein-Ponndorf-Verley reductions mediated by lanthanide-alkoxide-functionalized mesoporous silicates
Stud. Surf. Sci. Catal. 1998, 117, 413-420. Link

36.

R. Anwander, C. Palm, J. Stelzer, O. Groeger and G. Engelhardt
Silazane-silylation of mesoporous silicates: towards tailor-made support materials
Stud. Surf. Sci. Catal. 1998, 117, 135-142. Link

35.

H. W. Görlitzer, M. Spiegler, and R. Anwander
Synthesis and Structural Characterization of Rare Earth Metal Disulfonamide Complexes
Eur. J. Inorg. Chem. 1998, 1009-1014. Link

34.

R. Anwander, C. Palm, O. Groeger, and G. Engelhardt
Formation of Lewis Acidic Support Materials via Chemisorption of Trimethylaluminum on Mesoporous Silicate MCM-41
Organometallics 1998, 17, 2027-2036. Link

33.

W. T. Klooster, R. S. Lu, R. Anwander, W. J. Evans, T. F. Koetzle, and R. Bau
Neutron Diffraction Study of Nd[AlMe4]3x0.5 Al2Me6 at 100 K: The First Detailed Look at a Bridging Methyl Group with a Trigonal Bipyramidal Carbon Atom
Angew. Chem. 1998, 110, 1326-1329; Angew. Chem. Int. Ed. Engl. 1998, 37, 1268-1270. Link

32.

J. Eppinger, E. Herdtweck, and R. Anwander
Synthesis and characterisation of alkali metal bis(dimethylsilyl) amides: an infinite all–planar ladder structure of the unsolvated sodium derivative
Polyhedron 1998,17, 1195-1201. Link
(special issue to commemorate the 50th birthday of Prof. W. A. Herrmann)

31.

R. Anwander
Selbstorganisation in der Organolanthanoid-Chemie: von Ringen und Clustern
Angew. Chem. 1998, 110, 619-622; Angew. Chem. Int. Ed. Engl. 1998, 37, 599-602. Link

30.

R. Anwander, O. Runte, J. Eppinger, G. Gerstberger, E. Herdtweck, and M. Spiegler
Synthesis and structural characterisation of rare earth dimethylsilylamides and their surface organometallic chemistry on mesoporous MCM-41
J. Chem. Soc., Dalton Trans. 1998, 847-858. Link

29.

R. Anwander, F. C. Munck, W. Scherer, T. Priermeier, O. Runte, and W. A. Herrmann
Volatile Donor-functionalized Alkoxy Derivatives of Lutetium and Their Structural Characterization
Inorg. Chem. 1997, 36, 3545-3552. Link

28. R. Anwander
Buchrezension: Episodes from the History of Rare Earth Elements
Angew. Chem. 1997, 109, 1414-1415; Angew. Chem. Int. Ed. Engl.1997, 36, 1414-1415.
27.

W. A. Herrmann, J. Eppinger, M. Spiegler, O. Runte, and R. Anwander
b-Si-H Agostic Rigidity in a Solvent-free Indenyl-derived Ansa-Yttrocene Silylamide
Organometallics 1997, 16, 1813-1815. Link

26.
 

W. A. Herrmann, F. C. Munck, G. R. J. Artus, O. Runte, and R. Anwander
1,3-Dimethylimidazol-2-ylidene – Carbene Donor Ligation in Lanthanide Silylamide Complexes
Organometallics 1997, 16, 682-688. Link

25.

R. Anwander and R. Roesky
Grafting of versatile lanthanide silylamide precursors onto mesoporous MCM-41
J. Chem. Soc., Dalton Trans. 1997, 137-138. Link

24.

R. Anwander
Rare Earth Metals in Homogeneous Catalysis
in Applied Homogeneous Catalysis with Organometallic Compounds (Eds.: B. Cornils and W.A. Herrmann)
VCH Verlagsgesellschaft mbH, Weinheim, 1996, pp. 866-892.

23.

R. Anwander
Routes To Monomeric Lanthanide Alkoxides
Top. Curr. Chem. 1996, 179, 149-245. Link

22.

R. Anwander
Lanthanide Amides
Top. Curr. Chem. 1996, 179, 33-112. Link

21.

R. Anwander and W. A. Herrmann:
Features of Organolanthanide Complexes
Top. Curr. Chem. 1996, 179, 1-32. Link

20.

O. Runte, T. Priermeier and R. Anwander
Synthesis of highly soluble yttrium-salen complexes and the X-ray structure of N,N´-Bis-(3,5-di-tert-butyl-salicylidene)ethylenediamine- [bis(dimethylsilyl)amido]yttrium
Chem. Commun. 1996, 1385-1386. Link

19. W. J. Evans, R. Anwander, J. W. Ziller, and S. I. Khan
Heteropolyagostic Interactions in Lanthanide(III) Di(ipropyl)amido Complexes
Inorg. Chem. 1995, 34, 5927-5930. Link
18.

R. Anwander und W. A. Herrmann
Die Entdeckung der Röntgenstrahlinterferenzen an Kristallen
Chem. Unserer Zeit 1995, 29, 241-248. Link

17.
 

W. J. Evans, R. Anwander, U. H. Berlekamp, and J. W. Ziller
Synthesis and Structure of Lanthanide Complexes Derived from the O,N-Chelating, Bis(methylpyridine) Substituted Alcohol, HOC(CMe3)(2-CH2-NC5H3-Me-6)2
Inorg. Chem. 1995, 34, 3583-3588. Link

16.
 

W. J. Evans, R. Anwander, and J. W. Ziller
Inclusion of Al2Me6 in the Crystalline Lattice of the Organometallic Complexes LnAl3Me12
Organometallics 1995, 14, 1107-1109. Link

15.

W. J. Evans, R. Anwander, M. A. Ansari, and J. W. Ziller
Sm(II) with Oxygen Donor Ligands. The First Structurally Characterized Sm(II)-Aryloxide Complex, [KSm(OC6H2But2-2,6-Me-4)3(THF)]n
Inorg. Chem. 1995, 34, 5-6. Link

14.

W. A. Herrmann, R. Anwander, F. C. Munck, W. Scherer, V. Dufaud, N. W. Huber und G. R. J. Artus
Lanthanoiden-Komplexe, IX. Reaktivitätsbestimmender Einfluß der Ligandenkonstitution bei Seltenerdamiden: Herstellung und Struktur sterisch überladener Alkoxid-Komplexe
Z. Naturforsch. 1994, 49B, 1789-1797.
(special issue to commemorate the 60th birthday of Prof. H. Schmidbaur)

13.

W. J. Evans, R. Anwander, R. Doedens, and J. W. Ziller
The Use of Heterometallic Bridging Moieties To Generate Tractable Lanthanide Complexes of Small Ligands
Angew. Chem. 1994, 106, 1725-1728; Angew. Chem. Int. Ed. Engl. 1994, 33, 1641-1644. Link

12.

W. A. Herrmann, R. Anwander, V. Dufaud und W. Scherer
Molekulare Siloxankomplexe — Modellsysteme für silikatgeträgerte Katalysatoren?
Angew. Chem. 1994, 106, 1338-1340; Angew. Chem. Int. Ed. Engl. 1994, 33, 1285-1286. Link

11.

R. Anwander, W. A. Herrmann, F. C. Munck und W. Scherer
Lanthanoiden-Komplexe, VI. Monomerere homoleptische Ln(RDoCp)3-Komplexe (Ln = La, Nd) mit aminofunktionalisiertem Cyclopentadienyl-Liganden
J. Organomet. Chem. 1993, 462, 163-174. Link
(special issue to commemorate the 65th birthday of Prof. M. L. Lappert)

10.

W. A. Herrmann, R. Anwander, H. Riepl, W. Scherer, and C. R. Whitaker

General Synthesis and Metal Complexes of Fused-Ring Bicyclic Cyclopentadienes
Organometallics 1993,12, 4342-4349. Link

9.

W. A. Herrmann, R. Anwander und W. Scherer
Lanthanoiden-Komplexe, V. Strukturchemie ein- und zweikerniger Seltenerdalkoxide
Chem. Ber. 1993, 126, 1533-1539. Link

8.

W. A. Herrmann, N. W. Huber, R. Anwander und T. Priermeier
Monomere flüchtige Alkoxide von Chrom und Bismut
Chem. Ber. 1993, 126, 1127-1130. Link

7.

R. Anwander
Flüchtige Lanthanoid-Komplexe für die Gasphasenabscheidung
Doktorarbeit, Technische Universität München, 1993. Link

6.

W. A. Herrmann, R. Anwander, F. C. Munck und W. Scherer
Lanthanoiden-Komplexe, IV. Alkyl- und donorsubstituierte Cyclopentadienyl-Komplexe des Neodyms
Chem. Ber. 1993, 126, 331-337. Link

5.

W. A. Herrmann, R. Anwander und M. Denk
Lanthanoiden-Komplexe, III. Flüchtige Neodym- und Yttrium-Alkoxide mit neuen sperrigen Chelatliganden
Chem. Ber. 1992, 125, 2399-2405. Link

4.

R. Anwander und W. A. Herrmann
Flüchtige Seltenerdmetall-Alkoxide, insbesondere zur Herstellung von Seltenerdmetall-Oxiden, sowie Alkohole zum Synthetisieren von flüchtigen Verbindungen
P 4208689.2 v. 18.3.92, Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH., München. Link

3.

W. A. Herrmann, R. Anwander, M. Kleine, K. Öfele, J. Riede und W. Scherer
Lanthanoiden-Komplexe, II. Tris(t-butylcyclopentadienyl)neodym, -dysprosium und -thulium. Kristall- und Molekülstruktur von Hydroxybis(t-butylcyclopentadienyl)neodym und -dysprosium
Chem. Ber. 1992, 125, 2391-2397. Link

2.

W. A. Herrmann, R. Anwander, M. Kleine und W. Scherer
Lanthanoiden-Komplexe, I. Solvensfreie Alkoxid-Komplexe des Neodyms und Dysprosiums. Kristall- und Molekülstruktur von trans-Bis(acetonitril)tris[tri(tert.butyl)methoxy]neodym
Chem. Ber. 1992, 125, 1971-1979. Link

1.

W. A. Herrmann, J. K. Felixberger, R. Anwander, E. Herdtweck, P. Kiprof, and J. Riede
Multiple Bonds between Transition Metals and Main-Group Elements. 73. Synthetic Routes to Rhenium (V) Alkyl and Rhenium(VII) Alkylidyne Complexes. X-Ray Crystal Structures of (h5-C5Me5)Re(=O)(CH3)-[CH2C(CH3)3] and (h5-C5Me5)(Br)3ReCC(CH3)3
Organometallics 1990, 9, 1434-1443. Link

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