Institut für Anorganische Chemie

Publikationen 2016 - 2020

F. Fetzer, A. Maier, M. Hodas, O. Geladari, K. Braun, A. J. Meixner, F. Schreiber, A. Schnepf, M. Scheele, 
Nat. Commun. 2020, 11, 6188; DOI:10.1038/s41467-020-19461-x
„Structural order enhances charge carrier transport in self-assembled Au-nanoclusters.”

M. Diecke, C. Schrenk, A. Schnepf,
Angew. Chem. 2020, 132, 14525 - 14529; DOI: 10.1002/ange.202006454;
Angew. Chem. Int. Ed. 2020, 59, 14418 - 14422; DOI: 10.1002/anie.202006454.
„Synthesis and Characterization of the Highly Unstable Metalloid Cluster Ag64Cl8(PnBu3)16

S. Kenzler, C. Schrenk, A. Schnepf,
Dalton Trans., 2020, 49, 10765 - 10771; DOI: 10.1039/D0DT02262D
„Au54(Et3P)18Cl12: A structurally related Cluster to Au32(Et3P)12Cl8 gives insight into the formation process.”

L. Preißing, C. Schrenk, A. Schnepf,
Z. Anorg. Allg. Chem. 2020646, 653 - 658, DOI: zaac.201900296
„Ge4Cl4[MCp(CO)3]4 (M = Cr, Mo, W): A Series of Transition Metal Substituted Four-membered Cyclogermanes Ge4Cl4[MCp(CO)3]4.”

N. C. Michenfelder, C. Gienger, M. Dilanas, A. Schnepf, A.-N. Unterreiner,
Molecules, 2020, 25, 2639; DOI:10.3390/molecules25112639.
„Photoexcitation of Ge9− Clusters in THF: New Insights into the Ultrafast Relaxation Dynamics and the Influence of the Cation”

T. Kunz, C. Schrenk, A. Schnepf,
Inorg. Chem. 2020, 59, 6279 – 6286. DOI: 10.1021/acs.inorgchem.0c00379
“Cascade-Reaction Leading to an Intramolecular [2 + 4] Cycloaddition of a Phenyl Group by a Reactive Ge=Si Double Bond”

N. C. Michenfelder, C. Gienger, A. Schnepf, A.-N. Unterreiner, 
Dalton Trans. 2019, 48, 15577 – 15582.  DOI: 10.1039/C9DT02091H.
„The influence of the FeCp(CO)2+ moiety on the dynamics of the metalloid [Ge9(Si(SiMe3)3)3] cluster in thf:
synthesis and characterization by time-resolved absorption spectroscopy”

M. Binder, C. Schrenk, A. Schnepf, 
Chem. Commun. 201955, 12148 - 12151, DOI:10.1039/C9CC07099K
„Sn20(SitBu3)10Cl2 – the largest metalloid group 14 cluster shows a raspberry-like arrangement of smaller units.”

T. Geiger, A. Haupt, C. Maichle-Mössmer, C. Schrenk, A. Schnepf, H. Bettinger, 
J. Org. Chem201984, 10120-10135, DOI:10.1021/acs.joc.9b01317
„Photodimerization of 2- and 2,3-disubstituted anthracenes: influence of steric interactions and London dispersion on diastereoselecitvity"

T. Kunz, C. Schrenk, A. Schnepf,
Chem. Eur. J201925, 7210 – 7217, DOI:10.1002/chem.201900573
„Reactions of GeCl2 with the Thiolate LiSC(SiMe3)3: From thf Activation to Insertion of GeCl2 Molecules into C-S Bonds.”

S. Kenzler, F. Fetzer, C. Schrenk, N. Pollard, A. R. Frojd, A. Z. Clayborne, A. Schnepf, 
Angew. Chem2019131, 5962 – 5966, DOI: 10.1002/ange.201900644
Angew. Chem. Int. Ed201958, 5902 – 5905, DOI: 10.1002/anie.201900644
„Synthesis and Characterization of Three Multi‐Shell Metalloid Gold Clusters Au32(R3P)12Cl8.”

L. Preißing, C. Schrenk, A. Schnepf, 
Dalton Transactions201948, 3831 – 3834, DOI: 10.1039/C9DT00097F 
„On the reaction of GeCl2·Dioxane with KFeCp(CO)2: Isolation and characterization of novel bimetallic clusters”

O. Kysliak, A. Schnepf,
Z. Anorg. Allg. Chem. 2019645, 335 – 339, DOI: 10.1002/zaac.201800296
„ Ge9{Si(SiMe3)3}2{Ge(SiMe3)3}]− : the mixed substituted metalloid Germanium cluster
and the intermetalloid cluster [ZnGe18{Si(SiMe3)3}4{Ge(SiMe3)3}2].”

J. Friedrich, C. Maichle-Mössmer, C. Schrenk, A. Schnepf, R. Anwander, 
Eur. J. Inorg. Chem. 2019, 79 – 90, DOI: 10.1002/ejic.201801150
„Ceric Ammonium Nitrate and Ceric Ammonium Chloride as Precursors for Ceric Siloxides: Ammonia and Ammonium Inclusion”

T. Kunz, A. Schnepf,
Chem. Eur. J201925, 144 – 157, DOI: 10.1002/chem.201804318
“Halides of the heavier group 14 homologues germanium tin and lead –
a journey through unusual compounds and oxidation states.”

O. Kysliak, D. D. Nguyen, A. Z. Clayborne, A. Schnepf,
Inorg. Chem. 2018, 57, 12603 – 12609, DOI: 10.1021/acs.inorgchem.8b01757
“[PtZn2Ge18(Hyp)8] (Hyp = Si(SiMe3)3) – A Neutral Polynuclear Chain Compound with Ge9(Hyp)3 Units”

S. Kenzler, M. Kotsch, A. Schnepf, 
Eur. J. Inorg. Chem2018, 3840 – 3848, DOI: 10.1002/ejic.201800595
“Synthesis and characterization of gold silyl compounds with different phosphine or
phosphite groups for reduction reactions.”

M. Binder, C. Schrenk, T. Block, R. Pöttgen, A. Schnepf,
Molecules 201823, 1022, DOI: 10.3390/molecules23051022
„LiGe(SiMe3)3: a New Substituent for the Synthesis of Metalloid Tin Clusters from Metastable SnI Halide Solutions.”

J. Hahn, S. Biswas, C. Maichle-Mössmer, C. Schrenk, A. Schnepf, H. F. Bettinger,
Pure Appl. Chem. 201890, 711 – 722, DOI: 10.1515/pac-2017-1103
„Borenium and boronium ions of 5,6-dihydro-dibenzo[c,e] [1,2]azaborinine and the reaction with non-nucleophilic base: trapping of a dimer and a trimer of BN-phenanthryne by 4,4′-di-tert-butyl-2,2′-bipyridine”

T. Kunz, C. Schrenk, A. Schnepf,
Angew. Chem. 2018130, 4152 – 4156, DOI: 10.1002/ange.201712247
Angew. Chem. Int. Ed201857, 4088 – 4092, DOI: 10.1002/anie.201712247
„Ge14Br8(PEt3)4: A Subhalide Cluster of Germanium”

S. Kenzler, C. Schrenk, A. R. Frojd, H. Häkkinen, A. Z. Clayborne, A. Schnepf,
Chem. Commun. 201854, 248 – 251, DOI: 10.1039/C7CC08014J
“Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups”

P. Schmidt, S. Fietze, C. Schrenk, A. Schnepf,
Z. Anorg. Allg. Chem. 2017, 643, 1759–1765, DOI: 10.1002/zaac.201700253
„Bulky Phenyl Modifications of the Silanide Ligand Si(SiMe3)3 – Synthesis and Reactivity.”

M. Binder, C. Schrenk, T. Block, R. Pöttgen, A. Schnepf,
Chem. Commun. 2017, 53, 11314 – 11317, DOI: 10.1039/C9CC06388A
„[Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]-: The longest intermetalloid chain compound of tin”

O. Kysliak, C. Schrenk, A. Schnepf,
Inorg. Chem. 2017, 56, 9693 – 9697, DOI: 10.1021/acs.inorgchem.7b01186.
„{[Si(SiMe3)3]2Ge9-SiMe2-(C6H4)-SiMe2-Ge9[Si(SiMe3)3]2K}- The connection of metalloid clusters via an organic linker”

H. F. Bettinger, R. Einholz, A. Göttler, M. Junge, M.-S. Sättele, A. Schnepf, C. Schrenk, S. Schundelmeier, B. Speiser,
Org. Chem. Frontiers, 2017, 4, 853 – 860, DOI: 10.1039/C7QO00117G
„6,6’,11,11’-Tetra((triisopropylsilyl)ethynyl)-anti-[2.2](1,4)tetracenophane: A Covalently Coupled Tetracene Dimer and its Structural, Electrochemical, and Photophysical Characterization.”

A. Schnepf in Structure and Bonding, Clusters – Contemporary Insight in Structure and Bonding,
(Ed. S. Dehnen), 2017, 174, 135 – 200, DOI: 10.1007/430_2015_5004
“Metalloid Clusters”

O. Kysliak, A. Schnepf, in Reedijk, J. (Ed.) Elsevier Reference Module in Chemistry,
Molecular Sciences and Chemical Engineering. Waltham, MA: Elsevier, 2017, DOI: 10.1016/B978-0-12-409547-2.13891-0.
“Metalloid Germanium Clusters as Starting Point for New Chemistry.“

O. Kysliak, T. Kunz, A. Schnepf,
Eur. J. Inorg. Chem. 2017, 805 – 810, DOI: 10.1002/ejic.201601134
„ Metalloid Ge9R3- clusters with various silyl substituents: from shielded to open cluster cores“

S. Kenzler, C. Schrenk, A. Schnepf,
Angew. Chem. 2017, 129, 402 – 406, DOI: 10.1002/ange.201609000
Angew. Chem. Int. Ed. 2017, 56, 393 – 396, DOI: 10.1002/anie.201609000
“Au108S24(PPh3)16: A Highly Symmetric Nanoscale Gold Cluster Confirms the General Concept of Metalloid Clusters.”

A. Schnepf,
GDCh Wochenschau 2016
“Gallium: Cluster, Licht und Neutrinos“

M. Binder, C. Schrenk, A. Schnepf,
J. Vis. Exp. 2016, 117, e54498, DOI: 10.3791/54498
„The Synthesis of [Sn10(Si(SiMe3)3)4]2- using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique”

O. Kysliak, C. Schrenk, A. Schnepf,
Chem. Eur. J. 2016, 22, 18787 – 18793DOI: 10.1002/chem.201603441
„ Reactivity of [Ge9{Si(SiMe3)3}3]- towards transition metal M2+ cations : coordination and redox chemistry “

F. Uhlemann, A. Schnepf,
Chem. Eur. J. 2016, 22, 10748 – 10753, DOI: 10.1002/chem.201601728
„IPr3Si3Cl5+: A Highly Reactive Cation with Silanide Character”

M. Kotsch, C. Gienger, C. Schrenk, A. Schnepf,
Z. Anorg. allg. Chem. 2016, 642, 670 – 675, DOI: 10.1002/zaac.201600137
„The Sterically Demanding Thiosilyl Group SSi(SiMe3)3 as a Ligand in Transition Metal Chemistry”

A. Schnepf,
Phosphorus, Sulfur, and Silicon and the Related Elements, 2016, 191, 662 – 664, DOI: 10.1080/10426507.2015.1128931
“Chemistry Applying Metalloid Tin Clusters.”

O. Kysliak, C. Schrenk, A. Schnepf,
Angew. Chem. 2016, 128, 3270 – 3274, DOI: 10.1002/ange.201510831
Angew. Chem. Int. Ed. 2016, 55, 3216 – 3219, DOI: 10.1002/anie.201510831
„Der größte metalloide Cluster der 14. Gruppe, Ge18[Si(SiMe3)3]6: eine Zwischenstufe auf dem Weg zu elementarem Germanium.”

O. Kysliak, A. Schnepf,
Dalton Trans. 2016, 45, 2404 – 2408, DOI: 10.1039/C5DT04022A
„{Ge9[Si(SiMe3)3]2}2- : A Starting Point for Mixed Substituted Metalloid Germanium Clusters.”