Institut für Anorganische Chemie

Dr. Manfred Manßen

Institut für Anorganische Chemie

Building A, 9A32
Universität Tübingen
phone: +49 7071 29 72438
fax: +49 7071 29 2436
Mail

Publications

14.

M. Fischer‡*, M. Manßen‡*, M. Schmidtmann, T. Klüner*, and R. Beckhaus*

Selective Propargylic C(sp³)–H Activation of Methyl-Substituted Alkynes versus [2 + 2] Cycloaddition at a Titanium Imido Template

Chem. Sci. 2021, DOI: 10.1039/D1SC04334J. Link

13.

M. Manßen, D. Deng, C. H. M. Zheng, R. DiPucchio, and D. Chen, L. L. Schafer*

Ureate Titanium Catalysts for Hydroaminoalkylation: Using Ligand Design to Increase Reactivity and Utility

ACS Catal. 2021, 11, 4550–4560. Link

12.

M. Manßen, and L. L. Schafer*

Early Transition Metal-Catalyzed Hydroaminoalkylation

Trends Chem. 2021, 3, 428-429. Link

11.

M. Manßen, and L. L. Schafer

Titanium Catalysis for the Synthesis of Fine Chemicals – Development and Trends

Chem. Soc. Rev. 2020, 49, 6947-6994. Link

10.

M. Manßen, A. Dierks, S. de Graaff, M. Schmidtmann, and R. Beckhaus*

Bis(η5:η1‐pentafulvene)niobium(V) Complexes: Efficient Synthons for Niobium Carbene and Imido Derivatives

Angew. Chem. Int. Ed. 2018, 57, 12062-12066. Link

9.

M. Manßen, M.-F. Meyer, M. Schmidtmann, and R. Beckhaus*

Direct Access to Terminal Titanocene Hydrazides via Bis(η5:η1-pentafulvene)titanium Complexes and 1,1-Diphenylhydrazine

Organometallics 201837, 4515-4520. Link

8.

M. Manßen, S. de Graaff, M.-F. Meyer, M. Schmidtmann, and R. Beckhaus*

Direct Access to Titanocene Imides via Bis(η5:η1-pentafulvene)titanium Complexes and Primary Amines

Organometallics 2018, 37, 4506-4514. Link

7.

M. Manßen, I. Weimer, C. Adler, M. Fischer, M. Schmidtmann, and R. Beckhaus*

From Organic Azides through Titanium Triazenido Complexes to Titanium Imides

Eur. J. Inorg. Chem. 2018, 131-136. Link

6.

M. Manßen, C. Kahrs, I. Töben, J.-H. Bölte, M. Schmidtmann, and R. Beckhaus*

From Five to Seven: Ring Expansion of Monoazadiene Titanium Complexes by Insertion of Aldehydes, Ketones and Nitriles

Chem. Eur. J. 2017, 23, 15827-15833. Link

5.

M. Manßen, I. Töben, C. Kahrs, J.-H. Bölte, M. Schmidtmann, and R. Beckhaus*

Reactions of Secondary Allylamines with Bis(η5:η1-pentafulvene)titanium Complexes: Selective Formation of Monoazabutadiene Titanium Complexes by N–H and C–H Bond Activation

Organometallics 2017, 36, 2973-2981. Link

4.

M. Manßen, N. Lauterbach, T. Woriescheck, M. Schmidtmann, and R. Beckhaus*

Reactions of Secondary Amines with Bis(η5:η1-pentafulvene)titanium Complexes: Formation of Titanium Amides and Titanaaziridines

Organometallics 2017, 36, 867-876. Link

3.

M. Manßen, M. Schmidtmann, and R. Beckhaus*

Crystal structure of 1,1-bis(η5-adamantylcyclopentadienyl)-3-phenyl-2-trimethylsilyl-2,3-dihydroisotitanazole, C42H55NSiTi. Z

Kristallogr. NCS 2017, 232, 671-673. Link

2.

M. Manßen, C. Adler, and R. Beckhaus*

Flexible Structural Features of Pentafulvene Titanium Derivatives: Isolation and Characterization of NHC Complexes

Chem. Eur. J. 2016, 22, 4405-4407. Link

1.

M. Manßen, N. Lauterbach, J. Dörfler, M. Schmidtmann, W. Saak, S. Doye, and R. Beckhaus*

Efficient Access to Titanaaziridines by C–H Activation of N‐Methylanilines at Ambient Temperature

Angew. Chem. Int. Ed. 2015, 54, 4383-4387. Link

Books

1.

L. L. Schafer, M. Manßen, P. Edwards, E. Lui, and C. Dunbar
Titanium Catalyzed Synthesis of Amines and N-Heterocycles

Advances in Organometallic Chemistry 2020, 74, 405-468, Redaktion: Prof. Pedro Perez. Link

 

Patents

1.

L. L. Schafer, M. Manßen; D. Deng, R. DiPucchio, and S. Scott
Methods for Hydroaminoalkylation of Olefins and Group 4 Metal Complexes Useful in such Methods

US Patent Application Serial No. 63/130,306.

 

Curriculum vitae

born 06-08-1990 in Leer (Ostfriesland, Germany), married

Studies at the Universität Oldenburg

2009 - 2012
Studium: B. Sc. Chemie

Synthesis of Novel Titanium Alkoxides Universität Oldenburg (Prof. Dr. Rüdiger Beckhaus)

2012 - 2014
Studium: M. Sc. Chemie

Formation and Reactions of Titanium Aziridines – Based on Secondary Amines Universität Oldenburg (Prof. Dr. Rüdiger Beckhaus)

2014 - 2018
Promotion

Efficient N–H/C–H Bond Activations via Bis(pentafulvene) Titanium and Niobium Complexes – Coordination Chemistry and Application Universität Oldenburg (Prof. Dr. Rüdiger Beckhaus)

2019 - 2021
Postdoc Position

Department of Chemistry, University of British Columbia, Vancouver (Prof. Dr. Laurel Schafer)

08.2021 - until now
Gastwissenschaftler

Universität Tübingen (Prof. Dr. Reiner Anwander)

Awards

08/2021
Rückkehrstipendium

Alexander von Humboldt-Stiftung

2019 – 2021
Feodor-Lynen-Stipendium

Alexander von Humboldt-Stiftung

2016 – 2017
Heinz-Neumüller-Stipendium

CEWE-Stiftung

2014
Deutschlandstipendium

2013
Niedersachsenstipendium