Paleoenvironmental investigations in geochemistry try to reconstruct temporal changes in Earth’s atmosphere, hydrosphere and geosphere system. Formation and deposition of any sediment thus interacts with one or more of these spheres leading to physical, chemical and biological processes influencing the abundance of elements and their isotopes within the sediment.
Of particular interest in this theme are the profound changes during the Archean-Proterozoic transition, when oxygen levels rose dramatically during a first Great Oxidation Event (GOE: 2.45 to 2.32 Ga). To better resolve Earth’s oxygenation before the GOE we apply different isotope systems of redox-sensitive elements as for example Cr, Fe, Mo and W. Especially the combination of these different proxies might allow us to set better constraints on the early rise of free oxygen in the hydro- and atmosphere.