Publications 2011 - 2015

[83]

O. Kysliak, C. Schrenk, A. Schnepf,
Inorg. Chem. 2015, 54, 7083 – 7088, DOI: 10.1021/acs.inorgchem.5b01130
„{Ge₉[Si(SiMe₃)₂(SiPh₃)]₃}^˗: Ligand Modification in Metalloid Germanium Cluster Chemistry."

[82]

M. Klinger, C. Schenk, F. Henke, P. A. Clayborne, A. Schnepf, A.-N. Unterreiner,
Chem. Commun. 2015, 51, 12278 – 12281, DOI: 10.1039/C5CC04513D
“UV photoexcitation of a dissolved metalloid Ge₉ cluster compound and its extensive ultrafast response.”

[81]

C. Schrenk, B. Gerke, R. Pöttgen, A. Clayborne, A. Schnepf,
Chem. Eur. J. 2015, 21, 8222 – 8228, DOI: 10.1002/chem.201500550
„Reactions with a Metalloid Tin Cluster {Sn₁₀[Si(SiMe₃)₃]₄}^2–: Ligand Elimination versus Coordination Chemistry.”

[80]

C. Schrenk, F. Winter, R. Pöttgen, A. Schnepf,
Chem. Eur. J. 2015, 21, 2992 – 2997, DOI: 10.1002/chem.201405595
„{Sn₁₀[Si(SiMe₃)₃]₄}^2- : A high reactive metalloid tin cluster with an open ligand shell for further applications.”

[79]

M. Neumeier, C. Schenk, H. Schnöckel, A. Schnepf,
Z. Anorg. Allg. Chem. 2014, 640, 2701 – 2707, DOI: 10.1002/zaac.201400280
„The influence of a single transition metal atom on the reactivity of main group metal clusters in the gas phase”

[78]

J. Laudien, D. Naglav, C. Groß-Heitfeld, K.B. Ferenz, H. de Groot, C. Mayer, S.Schulz, A. Schnepf, M. Kirsch,
J. Microencapsul. 2014, 31, 738 – 745, DOI: 10.3109/02652048.2014.918668
„Perfluorodecalin-soluble fluorescent dyes for the monitoring of circulating nanocapsules with intravital fluorescence microscopy”

[77]

R. Klink, C. Schrenk, A. Schnepf,
Dalton Trans. 2014, 43, 16097 – 16104, DOI: 10.1039/C4DT02372B
„Si(SiMe₃)₂SiPh₃ – A Ligand for Novel Sub-Valent Tin Cluster Compounds”

[76]

F. Uhlemann, R. Köppe, A. Schnepf,
Z. Anorg. Allg. Chem. 2014, 640, 1658 – 1664, DOI: 10.1002/zaac.201400122
„Synthesis of metastable Si(II)X₂ solutions (X = F, Cl). A Novel Binary Halide for Synthesis”

[75]

C. Schrenk, A. Schnepf,
Rev. Inorg. Chem. 2014, 34, 93 – 118, DOI: 10.1515/revic-2013-0016
„Metalloid Sn clusters: properties and the novel synthesis via a disproportionation reaction of a monohalide”

[74]

D. Himmel, I. Krossing, A. Schnepf,
Angew. Chem. 2014, 126, 6159 – 6160, DOI: 10.1002/ange.201403078
Angew. Chem. Int. Ed. 2014, 53, 6047 – 6048, DOI: 10.1002/anie.201403078
„Dativ oder nicht Dativ?“

[73]

A. Schnepf, H. Schnöckel,
Angew. Chem. 2014, 126, 3124 – 3127, DOI: 10.1002/ange.201310158
Angew. Chem. Int. Ed. 2014, 53, 3064 – 3066, DOI: 10.1002/anie.201310158
„Nanoscaled Molecular Silver Cluster Compounds in Gram Quantities”

[72]

D. Himmel, I. Krossing, A. Schnepf,
Angew. Chem. 2014, 126, 378 – 382, DOI: 10.1002/ange.201300461
Angew. Chem. Int. Ed. 2014, 53, 370 – 374, DOI: 10.1002/anie.201300461
„Dative Bindungen bei Hauptgruppenelementverbindungen: ein Plädoyer für weniger Pfeile“

[71]

C. Schrenk, A. Schnepf,
Main Group Metal Chem. 2013, 36, 161 – 167, DOI: 10.1515/mgmc-2013-0031
“{Sn₁₀Si[Si(SiMe₃)₃]₄(SiMe₃)₂}^2- : Cluster enlargement via degradation of labile ligands.”

[70]

Margaret A. Hanson, Andreas Schnepf, Victor V. Terskikh, Yining Huang, Kim M. Baines,
Austr. J. Chem. 2013, 66, 1202 – 1210, DOI: 10.1071/CH13122
“Characterization of Germanium Monohalides by Solid-State NMR Spectroscopy and First Principles Quantum Chemical Calculations”

[69]

D. Naglav, B. Tobey, A. Schnepf,
Eur. J. Inorg. Chem. 2013, 4146 – 4149, DOI: 10.1002/ejic.201300401
„GaCp: Application as a ligand in coordination chemistry – Similarities and differences to GaCp*“

[68]

C. Schenk, F. Henke, A. Schnepf,
Angew. Chem. 2013, 125, 1883 – 1887, DOI: 10.1002/anie.201207224
Angew. Chem. Int. Ed. 2013, 52, 1834 – 1838, DOI: 10.1002/anie.201207224
„Ge₁₂[FeCp(CO)₂]₈[FeCpCO]₂ – A Ge₁₂ Core Resembles the Arrangement of the High Pressure Modification Germanium(II)“

[67]

D. Naglav, B. Tobey, S. Harder, A. Schnepf,
Z. Anorg. Allg. Chem. 2013, 639, 354–359, DOI: 10.1002/zaac.201200242
„GeCp^big₂ [Cp^big = C₅(CH₂C₆H₄-iPr)₅: A Flexible Sandwich Molecule.”

[66]

C. Schrenk, F. Winter, R. Pöttgen, A. Schnepf,
Inorg. Chem. 2012, 51, 8583−8588, DOI: 10.1021/ic3011647
„{Sn₉[Si(SiMe₃)₃]₂}^2-: A metalloid Tin Cluster Compound With a Sn₉ Core of Oxidation State Zero.”

[65]

C. Schrenk, J. Helmlinger, A. Schnepf, 
Z. Anorg. allg. Chem. 2012, 638, 589 – 593, DOI: 10.1002/zaac.201100364
„{Sn₁₀[Si(SiMe₃)₃]₅}^- : An anionic metalloid tin cluster from an isolable Sn(I) Halide solution.“

[64]

C. Schrenk, M. Neumaier, A. Schnepf,
Inorg. Chem. 2012, 51, 3989 – 3995, DOI: 10.1021/ic201730g
“{Sn₉[Si(SiMe₃)₃]₃}^- and {Sn₈Si[Si(SiMe₃)₃]₃}^- : Variations of the E₉ Cage of Metalloid Group 14 Clusters.”

[63]

C. Schenk, R. Köppe, H. Schnöckel, A. Schnepf,
Eur. J. Inorg. Chem. 2011, 3681 – 3685, DOI: 10.1002/ejic.201100672
„A Convenient Synthesis of Cyclopentadienylgallium: The Awakening of a Sleeping Beauty in Organometallic Chemistry“

[62]

C. Schrenk, A. Kubas, K. Fink, A. Schnepf,
Angew. Chem. 2011, 123, 7411 – 7415, DOI: 10.1002/anie.201102662
Angew. Chem. Int. Ed. 2011 50, 7237 – 7277, DOI: 10.1002/anie.201102662
“Sn₄Si[Si(SiMe₃)₃]₄[SiMe₃]₂: A Model Compound for the Unexpected First-Order Transition from a Singlet Biradicaloid to a Classical Bonded Molecule”

[61]

C. Schenk, F. Henke, A. Schnepf,
Phosphorus, Sulfur and Silicon and the Related Elements, 2011, 186, 1370 – 1374, DOI: 10.1080/10426507.2010.543108
“Metalloid cluster compounds of group 14: Bonding properties and subsequent reactions.”

[60]

F. Henke, C. Schenk, A. Schnepf,
Dalton Trans., 2011, 40, 6704 - 6710, DOI: 10.1039/C1DT10096C
„[Si(SiMe₃)₃]₃Ge₉M(CO)₃^- (M = Cr, Mo, W): Coordination Chemistry with metalloid Clusters.”

[59]

H. Schnöckel, A. Schnepf,
in The Group 13 Metals Aluminium, Gallium, Indium and Thallium, 1. Edition (Eds. S. Aldridge, A. J. Downs), 2011, 402 – 487, WILEY-VCH.
“Aluminium and Gallium Clusters: Metalloid Clusters and their Relationship to the Bulk Phases, to Naked Clusters and to Nanoscaled Materials.”

[58]

C. Schenk, A. Kracke, K. Fink, A. Kubas, W. Klopper, M. Neumaier, H. Schnöckel, A. Schnepf,
J. Am. Chem. Soc. 2011, 133, 2518 – 2524, DOI: 10.1021/ja107446z
“The Formal Combination of Three Singlet Biradicaloid Entities to a Singlet Hexaradicaloid Metalloid Ge₁₄[Si(SiMe₃)₃]₅Li₃(THF)₆ Cluster.”

[57]

H. Schnöckel, A. Schnepf, R. L. Whettten, C. Schenk, P. Henke,
Z. Anorg. Allg. Chem. 2011, 637, 15 – 23, DOI: 10.1002/zaac.201000333
“A Chemical View of the Giant Au₁₀₂(SR)₄₄ (SR = P-Mercaptobenzoic Acid) Cluster:
Metalloid Aluminum and Gallium Clusters as Path Making Examples of This Novel Type Open Our Eyes for Structure and Bonding of Metalloid Au_n(SR)_m (n > m) Clusters.”