Publications 2016 - 2020
[120]
F. Fetzer, A. Maier, M. Hodas, O. Geladari, K. Braun, A. J. Meixner, F. Schreiber, A. Schnepf, M. Scheele,
Nat. Commun. 2020, 11, 6188; DOI:10.1038/s41467-020-19461-x
„Structural order enhances charge carrier transport in self-assembled Au-nanoclusters.”
[119]
M. Diecke, C. Schrenk, A. Schnepf,
Angew. Chem. 2020, 132, 14525 - 14529; DOI: 10.1002/ange.202006454;
Angew. Chem. Int. Ed. 2020, 59, 14418 - 14422; DOI: 10.1002/anie.202006454.
„Synthesis and Characterization of the Highly Unstable Metalloid Cluster Ag64Cl8(PnBu3)16”
[118]
S. Kenzler, C. Schrenk, A. Schnepf,
Dalton Trans., 2020, 49, 10765 - 10771; DOI: 10.1039/D0DT02262D
„Au54(Et3P)18Cl12: A structurally related Cluster to Au32(Et3P)12Cl8 gives insight into the formation process.”
[117]
L. Preißing, C. Schrenk, A. Schnepf,
Z. Anorg. Allg. Chem. 2020, 646, 653 - 658, DOI: zaac.201900296
„Ge4Cl4[MCp(CO)3]4 (M = Cr, Mo, W): A Series of Transition Metal Substituted Four-membered Cyclogermanes Ge4Cl4[MCp(CO)3]4.”
[116]
N. C. Michenfelder, C. Gienger, M. Dilanas, A. Schnepf, A.-N. Unterreiner,
Molecules, 2020, 25, 2639; DOI:10.3390/molecules25112639.
„Photoexcitation of Ge9− Clusters in THF: New Insights into the Ultrafast Relaxation Dynamics and the Influence of the Cation”
[115]
T. Kunz, C. Schrenk, A. Schnepf,
Inorg. Chem. 2020, 59, 6279 – 6286. DOI: 10.1021/acs.inorgchem.0c00379
“Cascade-Reaction Leading to an Intramolecular [2 + 4] Cycloaddition of a Phenyl Group by a Reactive Ge=Si Double Bond”
[114]
N. C. Michenfelder, C. Gienger, A. Schnepf, A.-N. Unterreiner,
Dalton Trans. 2019, 48, 15577 – 15582. DOI: 10.1039/C9DT02091H.
„The influence of the FeCp(CO)2+ moiety on the dynamics of the metalloid [Ge9(Si(SiMe3)3)3] − cluster in thf:
synthesis and characterization by time-resolved absorption spectroscopy”
[113]
M. Binder, C. Schrenk, A. Schnepf,
Chem. Commun. 2019, 55, 12148 - 12151, DOI:10.1039/C9CC07099K
„Sn20(SitBu3)10Cl2 – the largest metalloid group 14 cluster shows a raspberry-like arrangement of smaller units.”
[112]
T. Geiger, A. Haupt, C. Maichle-Mössmer, C. Schrenk, A. Schnepf, H. Bettinger,
J. Org. Chem. 2019, 84, 10120-10135, DOI:10.1021/acs.joc.9b01317
„Photodimerization of 2- and 2,3-disubstituted anthracenes: influence of steric interactions and London dispersion on diastereoselecitvity"
[111]
T. Kunz, C. Schrenk, A. Schnepf,
Chem. Eur. J. 2019, 25, 7210 – 7217, DOI:10.1002/chem.201900573
„Reactions of GeCl2 with the Thiolate LiSC(SiMe3)3: From thf Activation to Insertion of GeCl2 Molecules into C-S Bonds.”
[110]
S. Kenzler, F. Fetzer, C. Schrenk, N. Pollard, A. R. Frojd, A. Z. Clayborne, A. Schnepf,
Angew. Chem. 2019, 131, 5962 – 5966, DOI: 10.1002/ange.201900644;
Angew. Chem. Int. Ed. 2019, 58, 5902 – 5905, DOI: 10.1002/anie.201900644
„Synthesis and Characterization of Three Multi‐Shell Metalloid Gold Clusters Au32(R3P)12Cl8.”
[109]
L. Preißing, C. Schrenk, A. Schnepf,
Dalton Transactions, 2019, 48, 3831 – 3834, DOI: 10.1039/C9DT00097F
„On the reaction of GeCl2·Dioxane with KFeCp(CO)2: Isolation and characterization of novel bimetallic clusters”
[108]
O. Kysliak, A. Schnepf,
Z. Anorg. Allg. Chem. 2019, 645, 335 – 339, DOI: 10.1002/zaac.201800296
„ Ge9{Si(SiMe3)3}2{Ge(SiMe3)3}]− : the mixed substituted metalloid Germanium cluster
and the intermetalloid cluster [ZnGe18{Si(SiMe3)3}4{Ge(SiMe3)3}2].”
[107]
J. Friedrich, C. Maichle-Mössmer, C. Schrenk, A. Schnepf, R. Anwander,
Eur. J. Inorg. Chem. 2019, 79 – 90, DOI: 10.1002/ejic.201801150
„Ceric Ammonium Nitrate and Ceric Ammonium Chloride as Precursors for Ceric Siloxides: Ammonia and Ammonium Inclusion”
[106]
T. Kunz, A. Schnepf,
Chem. Eur. J. 2019, 25, 144 – 157, DOI: 10.1002/chem.201804318
“Halides of the heavier group 14 homologues germanium tin and lead –
a journey through unusual compounds and oxidation states.”
[105]
O. Kysliak, D. D. Nguyen, A. Z. Clayborne, A. Schnepf,
Inorg. Chem. 2018, 57, 12603 – 12609, DOI: 10.1021/acs.inorgchem.8b01757
“[PtZn2Ge18(Hyp)8] (Hyp = Si(SiMe3)3) – A Neutral Polynuclear Chain Compound with Ge9(Hyp)3 Units”
[104]
S. Kenzler, M. Kotsch, A. Schnepf,
Eur. J. Inorg. Chem. 2018, 3840 – 3848, DOI: 10.1002/ejic.201800595
“Synthesis and characterization of gold silyl compounds with different phosphine or
phosphite groups for reduction reactions.”
[103]
M. Binder, C. Schrenk, T. Block, R. Pöttgen, A. Schnepf,
Molecules 2018, 23, 1022, DOI: 10.3390/molecules23051022
„LiGe(SiMe3)3: a New Substituent for the Synthesis of Metalloid Tin Clusters from Metastable SnI Halide Solutions.”
[102]
J. Hahn, S. Biswas, C. Maichle-Mössmer, C. Schrenk, A. Schnepf, H. F. Bettinger,
Pure Appl. Chem. 2018, 90, 711 – 722, DOI: 10.1515/pac-2017-1103
„Borenium and boronium ions of 5,6-dihydro-dibenzo[c,e] [1,2]azaborinine and the reaction with non-nucleophilic base: trapping of a dimer and a trimer of BN-phenanthryne by 4,4′-di-tert-butyl-2,2′-bipyridine”
[101]
T. Kunz, C. Schrenk, A. Schnepf,
Angew. Chem. 2018, 130, 4152 – 4156, DOI: 10.1002/ange.201712247
Angew. Chem. Int. Ed. 2018, 57, 4088 – 4092, DOI: 10.1002/anie.201712247
„Ge14Br8(PEt3)4: A Subhalide Cluster of Germanium”
[100]
S. Kenzler, C. Schrenk, A. R. Frojd, H. Häkkinen, A. Z. Clayborne, A. Schnepf,
Chem. Commun. 2018, 54, 248 – 251, DOI: 10.1039/C7CC08014J
“Au70S20(PPh3)12: an intermediate sized metalloid gold cluster stabilized by the Au4S4 ring motif and Au-PPh3 groups”
[99]
P. Schmidt, S. Fietze, C. Schrenk, A. Schnepf,
Z. Anorg. Allg. Chem. 2017, 643, 1759–1765, DOI: 10.1002/zaac.201700253
„Bulky Phenyl Modifications of the Silanide Ligand Si(SiMe3)3 – Synthesis and Reactivity.”
[98]
M. Binder, C. Schrenk, T. Block, R. Pöttgen, A. Schnepf,
Chem. Commun. 2017, 53, 11314 – 11317, DOI: 10.1039/C9CC06388A
„[Hyp-Au-Sn9(Hyp)3-Au-Sn9(Hyp)3-Au-Hyp]-: The longest intermetalloid chain compound of tin”
[97]
O. Kysliak, C. Schrenk, A. Schnepf,
Inorg. Chem. 2017, 56, 9693 – 9697, DOI: 10.1021/acs.inorgchem.7b01186.
„{[Si(SiMe3)3]2Ge9-SiMe2-(C6H4)-SiMe2-Ge9[Si(SiMe3)3]2K}- The connection of metalloid clusters via an organic linker”
[96]
H. F. Bettinger, R. Einholz, A. Göttler, M. Junge, M.-S. Sättele, A. Schnepf, C. Schrenk, S. Schundelmeier, B. Speiser,
Org. Chem. Frontiers, 2017, 4, 853 – 860, DOI: 10.1039/C7QO00117G
„6,6’,11,11’-Tetra((triisopropylsilyl)ethynyl)-anti-[2.2](1,4)tetracenophane: A Covalently Coupled Tetracene Dimer and its Structural, Electrochemical, and Photophysical Characterization.”
[95]
A. Schnepf in Structure and Bonding, Clusters – Contemporary Insight in Structure and Bonding,
(Ed. S. Dehnen), 2017, 174, 135 – 200, DOI: 10.1007/430_2015_5004
“Metalloid Clusters”
[94]
O. Kysliak, A. Schnepf, in Reedijk, J. (Ed.) Elsevier Reference Module in Chemistry,
Molecular Sciences and Chemical Engineering. Waltham, MA: Elsevier, 2017, DOI: 10.1016/B978-0-12-409547-2.13891-0.
“Metalloid Germanium Clusters as Starting Point for New Chemistry.“
[93]
O. Kysliak, T. Kunz, A. Schnepf,
Eur. J. Inorg. Chem. 2017, 805 – 810, DOI: 10.1002/ejic.201601134
„ Metalloid Ge9R3- clusters with various silyl substituents: from shielded to open cluster cores“
[92]
S. Kenzler, C. Schrenk, A. Schnepf,
Angew. Chem. 2017, 129, 402 – 406, DOI: 10.1002/ange.201609000
Angew. Chem. Int. Ed. 2017, 56, 393 – 396, DOI: 10.1002/anie.201609000
“Au108S24(PPh3)16: A Highly Symmetric Nanoscale Gold Cluster Confirms the General Concept of Metalloid Clusters.”
[91]
A. Schnepf,
GDCh Wochenschau 2016 www.aktuelle-wochenschau.de/2016
“Gallium: Cluster, Licht und Neutrinos“
[90]
M. Binder, C. Schrenk, A. Schnepf,
J. Vis. Exp. 2016, 117, e54498, DOI: 10.3791/54498
„The Synthesis of [Sn10(Si(SiMe3)3)4]2- using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique”
[89]
O. Kysliak, C. Schrenk, A. Schnepf,
Chem. Eur. J. 2016, 22, 18787 – 18793, DOI: 10.1002/chem.201603441
„ Reactivity of [Ge9{Si(SiMe3)3}3]- towards transition metal M2+ cations : coordination and redox chemistry “
[88]
F. Uhlemann, A. Schnepf,
Chem. Eur. J. 2016, 22, 10748 – 10753, DOI: 10.1002/chem.201601728
„IPr3Si3Cl5+: A Highly Reactive Cation with Silanide Character”
[87]
M. Kotsch, C. Gienger, C. Schrenk, A. Schnepf,
Z. Anorg. allg. Chem. 2016, 642, 670 – 675, DOI: 10.1002/zaac.201600137
„The Sterically Demanding Thiosilyl Group SSi(SiMe3)3 as a Ligand in Transition Metal Chemistry”
[86]
A. Schnepf,
Phosphorus, Sulfur, and Silicon and the Related Elements, 2016, 191, 662 – 664, DOI: 10.1080/10426507.2015.1128931
“Chemistry Applying Metalloid Tin Clusters.”
[85]
O. Kysliak, C. Schrenk, A. Schnepf,
Angew. Chem. 2016, 128, 3270 – 3274, DOI: 10.1002/ange.201510831
Angew. Chem. Int. Ed. 2016, 55, 3216 – 3219, DOI: 10.1002/anie.201510831
„Der größte metalloide Cluster der 14. Gruppe, Ge18[Si(SiMe3)3]6: eine Zwischenstufe auf dem Weg zu elementarem Germanium.”
[84]
O. Kysliak, A. Schnepf,
Dalton Trans. 2016, 45, 2404 – 2408, DOI: 10.1039/C5DT04022A
„{Ge9[Si(SiMe3)3]2}2- : A Starting Point for Mixed Substituted Metalloid Germanium Clusters.”