Publikationen | Universität Tübingen

	Publikationen
58	"Excited State Dynamics of the Carbazolato-Carbene Chromium(III) Complex [Cr(bimca)₂]⁺", J. Sander, F. Gauder, S. J. Schicktanz, T. Maulbetsch, J. Kalmbach, D. Zorn, R. Naumann, C. Förster, D. Kunz,* K. Heinze, Z. Anorg. Allg.* 2025, 651, e202500125. DOI: 10.1002/zaac.202500125.
57	"A Saddle-Shaped Expanded Porphyrinoid Fitting C₆₀", T. Maulbetsch, P. Frech, M. Scheele, K. W. Törnroos, D. Kunz, Chemistry—A European Journal* 2023, 29, e202302104. als preprint: "A saddle-shaped expanded porphyrinoid fitting C60", T. Maulbetsch, P. Frech, M. Scheele, K. W. Törnroos, D. Kunz, ChemRxiv, 2023*, DOI: 10.26434/chemrxiv-2023-pm414
56	"An Ylidic Cp and its Scandium Complexes in Equilibrium", F. Mazzotta, D. Kunz, Organometallics* 2021, 40, ASAP.
55	"The Fascinating Flexibility and Coordination Modes of a Pentamethylene Connected Macrocyclic CNC Pincer Ligand", R. Jordan, D. Kunz, Molecules* 2021, 26, 1669; Special Issue: "Carbon Ligands: From Fundamental Aspects to Applications"
54	"Carbenaporphyrins: No Longer Missing Ligands in N-Heterocyclic Carbene Chemistry", T. Maulbetsch, D. Kunz, Angew. Chem. Int. Ed.* 2021, 60, 2007-2012; Angew. Chem. 2021, 133, 2035-2040. als preprint: "Carbenaporphyrins: A Missing Ligand in N-Heterocyclic Carbene Chemistry", T. Maulbetsch, D. Kunz, ChemRxiv, 2020*, DOI: 10.26434/chemrxiv.12804032.v2.
53	"Group 6 Carbonyl Complexes of C‑Ylidic Cp Ligands", F. Mazzotta, K. W. Törnroos, D. Kunz, Organometallics* 2020, 39, 3590–3601.
52	"Electron-Deficient Imidazolium Substituted Cp Ligands and their Ru Complexes", F. Mazzotta, G. Zitzer, B. Speiser, D. Kunz, Chem. Eur. J.* 2020, 26, 16291–16305. Innentitelbild zu diesem Artikel:
51	"Deoxygenation of Epoxides with Carbon Monoxide", T. Maulbetsch, E. Jürgens, D. Kunz, Chem. Eur. J.* 2020, 26, 10634–10640. as preprint: "Iridium Catalyzed Deoxygenation of Epoxides with Carbon Monoxide", T. Maulbetsch, E. Jürgens, D. Kunz, ChemRxiv, 2019*, DOI: 10.26434/chemrxiv.9778703.v1.
50	"Nucleophilic Rh^I Catalyzed Selective Isomerization of Terminal Aziridines to Enamides", Y. Tian, D. Kunz, ChemCatChem* 2020, 12, 4272–4275.
49	"Synthesis and Reactivity of Cobalt(I) and Iridium(I) Complexes Bearing a Pentadentate N-Homoallyl-Substituted Bis(NHC) Pincer Ligand", Y. Tian, T. Maulbetsch, R. Jordan, K. W. Törnroos, D. Kunz, Organometallics* 2020, 39, 1221–1229.

2015 - 2019

2015 - 2019

48	"Ni(NHC) Catalyzed Rearrangement of 1‐Acyl‐2‐vinylcyclopropanes: Tackling a Mechanistic Puzzle by Combined Experimental and Computational Studies", A. Zens, F. Bauer, B. Kolb, F. Mannchen, P. Seubert, R. Forschner, K. S. Flaig, A. Köhn, D. Kunz, S. Laschat, Eur. J. Org. Chem.* 2019, 6285–6295.
47	"Nucleophilic Isomerization of Epoxides by Pincer-Rhodium Catalysts: Activity Increase and Mechanistic Insights", Y. Tian, E. Jürgens, K. Mill, R. Jordan, T. Maulbetsch, D. Kunz, ChemCatChem* 2019, 11, 4028–4035.
46	"Ylidic Cp-Ligands: Properties and New Developments", D. Kunz, F. Mazzotta, Adv. Organomet. Chem.* 2018, 70, 181-231.
45	"Regio- and chemoselective rearrangement of terminal epoxides into methyl alkyl and aryl ketones", Y. Tian, E. Jürgens, D. Kunz, Chem. Commun.* 2018, 54, 11340-11343.
44	"The coordinative flexibility of rigid phenanthroline-analogous di(NHC)-ligands", D. Kunz, Kim S. Flaig, Coord. Chem. Rev.* 2018, 377, 73-85.
43	"Synthesis of 1-Acyl-2-vinylcyclopropanes: Utilizing Copper-Carbenoid versus Sulfur Ylide Methodology", A. Zens, P. Seubert, B. Kolb, M. Wurster, M. Holzwarth, F. Mannchen, R. Forschner, B. Claasen, D. Kunz, S. Laschat, Synthesis* 2018, 50, 2367-2384.
42	"Generation of Annelated Dicarbenes and Their Alkali-Metal Chelate Complexes in Solution: Equilibrium between Hetero- and Homoleptic NHC Lithium Complexes", K. S. Flaig, B. Raible, V. Mormul, N. Denninger, C. Maichle-Mössmer, D. Kunz, Organometallics* 2018, 37, 1291-1303. Titelbild zu diesem Artikel:
41	"Synthesis of a lithium–cyclopentadienide complex by addition of LiNTf₂ to a zwitterionic fulvalene", D. Schmid, A. Seyboldt, K. Eichele, D. Kunz, Dalton Trans.* 2017, 46, 29-32.
40	"A Rigid CNC Pincer Ligand Acting as a Tripodal Cp Analogue", E. Jürgens, D. Kunz, Eur. J. Inorg. Chem.* 2017, 233–236.
39	"Synthesis of copper(II) and gold(III) bis(NHC)-pincer complexes", E. Jürgens, O. Back, J. J. Mayer, K. Heinze, D. Kunz, Z. Naturforsch.* 2016, 71b, 1011-1018. (Special Issue: Dedicated to Professor Gerhard Erker on the occasion of his 70th birthday)
38	"Optimised synthesis of monoanionic bis(NHC)-pincer ligand precursors and their Li-complexes", E. Jürgens, K. N. Buys, A.-T. Schmidt, S. K. Furfari, M. L. Cole, M. Moser, F. Rominger, D. Kunz, New J. Chem. 2016, 40, 9160-9169.
37	"Experimental and theoretical investigations on the high-electron donor character of pyrido-annelated N-heterocyclic carbenes", M. Nonnenmacher, D. M. Buck, D. Kunz, Beilstein J. Org. Chem.* 2016, 12, 1884-1896. (Thematic Series: "Organometallic chemistry" dedicated to the memory of Professor Peter Hofmann)
36	"Selective di- and monochlorination of pyridazine-annelated bis(imidazolium) salts", B. Raible, D. Kunz, Z. Naturforsch.* 2016, 71b, 659–666. (Special issue: Iminium Salts and Imines)
35	"Triazine Annelated NHC Featuring Unprecedented Coordination Versatility", D. M. Buck, D. Kunz, Organometallics* 2015, 34, 5335–5340.
34	"Reaction of Iron- and Tungsten Carbonyls with a Zwitterionic Fulvalene", D. Schmidt, A. Seyboldt, D. Kunz, Z. Anorg. Allg. Chem.* 2015, 641, 2228-2232. (Special Issue: Dedicated to Professor F. Ekkehardt Hahn on the Occasion of His 60th Birthday).
33	"Evidence for the Formation of Anionic Zerovalent Group 10 Complexes as Highly Reactive Intermediates", A. Seyboldt, B. Wucher, S. Hohnstein, K. Eichele, F. Rominger, K. W. Törnroos, D. Kunz, Organometallics* 2015, 34, 2717-2725.
32	"Identifying and Rationalizing the Conditions for the Isomerization of 1,5-Cyclooctadiene in Iridium Complexes by Experimental and Theoretical Mechanistic Studies", B. Raible, V. Gierz, D. Kunz, Organometallics* 2015, 34, 2018-2027.
31	"Selective rearrangement of terminal epoxides into methylketones catalysed by a nucleophilic rhodium–NHC–pincer complex ", E. Jürgens, B. Wucher, F. Rominger, K. W. Törnroos, D. Kunz, Chem. Commun.* 2015, 51, 1897-1900.
30	"Synthesis and Reactivity of an Ir(I) Carbonyl Complex Bearing a Carbazolide-bis(NHC) Pincer Ligand ", A. Seyboldt, B. Wucher, M. Alles, F. Rominger, C. Maichle-Mössmer, D. Kunz, J. Organomet. Chem.* 2015, 775, 202-208.

2010 - 2014

2010 - 2014

29	"Strongly Electron Donating Tridentate N-Heterocyclic Biscarbene Ligands for Rhodium and Iridium Catalysts", E. Jürgens, D. Kunz, in "Molecular Catalysts: Structure and Functional Design", L. H. Gade, P. Hofmann (Eds.), Kapitel 9, Wiley-VCH, Weinheim 2014.
28	"A Direct Synthesis of a Strongly Zwitterionic 6,6′-Diaminofulvalene", D. Schmid, A. Seyboldt, D. Kunz, Z. Naturforsch.* 2014, 69b, 580-588. (Spezialheft: ImSaT-11)
27	"Electrosynthesis of Imidazolium Carboxylates", G. de Robillard, C. H. Devillers, D. Kunz, H. Cattey, E. Digard, J. Andrieu, Org. Lett. 2013, 15, 4410-4413.
26	"Dinuclear Coinage-Metal Complexes of Bis(NHC) Ligands: Structural Features and Dynamic Behavior of a Cu–Cu Complex", V. Gierz, A. Seyboldt, C. Maichle-Mössmer, K. W. Törnroos, M. T. Speidel, B. Speiser, K. Eichele, D. Kunz*, Organometallics 2012, 31, 7893–7901.
25	"Rhodium Complexes Bearing 1,10-Phenanthrolin Analogue Bis-NHC Ligands Are Active Catalysts for Transfer Hydrogenation of Ketones", V. Gierz, A. Urbanaite, A. Seyboldt, D. Kunz*, Organometallics 2012, 31, 7532–7538.
24	"Consequences of the One-Electron Reduction and Photoexcitation of Unsymmetric Bis-Imidazolium Salts", V. Gierz, J. Melomedov, C. Förster, C. Deißler, F. Rominger, D. Kunz, K. Heinze, Chem. Eur. J. 2012, 18, 10677-10688.
23	"Metal Complexes", D. Kunz, V. Gierz (Invs.), Merck Patent GmbH (Appl.), DE102011106849 (A1) Priorität: 15.12.2010.
22	"Straightforward Synthesis of Dipyrido-Annelated NHC-Palladium(II) Complexes by Oxidative Addition", V. Gierz, A. Seyboldt, C. Maichle-Mössmer, R. Fröhlich, F. Rominger, D. Kunz, Eur. J. Inorg. Chem.* 2012, 1423–1429.
21	"1,10-Phenanthrolin Analogue Pyridazine-Based N-Heterocycylic Carbene Ligands", V. Gierz, C. Maichle-Mössmer, D. Kunz, Organometallics* 2012, 31, 739–747.
20	"Theoretical investigation of the ¹³C NMR chemical shift – NCN angle correlation in N-heterocyclic carbenes", M. Nonnenmacher, D. Kunz, in "Modeling of Molecular Properties", P. Comba (Ed.), Kapitel 22, 349-363, Wiley-VCH, Weinheim 2011.
19	"Reduction of Dipyrido Ureas via 6-Alkyloxydipyrido[1,2-c;2',1'-e]imidazolium Salts", D. Kunz, C. Deißler, V. Gierz, F. Rominger, T. Oeser, Z. Naturforsch. 2010, 65b, 861-872. (Spezialheft: ImSaT-9).

2005 - 2009 (Habilitation)

2005 - 2009 (Habilitation)

18	"Preparation of 1,3-alkyl imidazolium salts", D. Kunz, C. Deissler, Offenlegungschrift, DE 102008014028 A1 20090917.
17	"Controlling the coordination modes of a new and highly flexible ligand bearing two N-hetrocyclic carbene moieties at a bipyridine backbone", C. Deißler, F. Rominger, D. Kunz, Dalton Trans.* 2009, 35, 7152-7167. "Controlling the coordination modes of a new and highly flexible ligand bearing two N-hetrocyclic carbene moieties at a bipyridine backbone", C. Deißler, F. Rominger, D. Kunz, Dalton Trans.* 2009, 35, 7152-7167.
16	"Synthesen, die gelingen - Klick-Chemie", D. Kunz, Chem. unserer Zeit 2009, 43, 224-230.
15	"Erste Röntgenstrukturanalysen von Rhodium(III)-η¹-Allyl-Komplexen und ein plausibler Mechanismus für allylische Isomerisierungsreaktionen", B. Wucher, M. Moser, S. A. Schumacher, F. Rominger, D. Kunz, Angew. Chem.* 2009, 121, 4481-4485; Angew. Chem. Int. Ed. 2009, 48, 4417-4421.
14	"Highly Ylidic Imidazoline-Based Fulvenes as Suitable Precursors for the Synthesis of Imidazolium-Substituted Metallocenes", D. Kunz, E. Ø. Johnsen, B. Monsler, F. Rominger, Chem. Eur. J.* 2008, 14, 10909-10914.
13	"Synthesis and Catalytic Properties of Rhodium(I) and Copper(I) Complexes Bearing Pyrido Anellated N-Heterocyclic Carbene Ligands", M. Nonnenmacher, F. Rominger, D. Kunz, Organometallics* 2008, 27, 1561-1568.
12	"Neue Synthesewege für N-heterocyclische Carbenkomplexe: Pyridin-Carben-Tautomerisierungen" (Highlight), D. Kunz, Angew. Chem.* 2007, 119, 3473-3476; Angew. Chem. Int. Ed. 2007, 46, 3405-3408.
11	"Synthesis of Symmetrically and Unsymmetrically Substituted N,N'-Diarylimidazolin-2-ones by Copper-Catalyzed Arylamination under Microwave-Assisted and Conventional Conditions", T. Hafner, D. Kunz, Synthesis* 2007, 1403-1411.
10	"Palladium(II) Complexes Bearing Methylene and Ethylene Bridged Pyrido-N-Heterocyclic Carbene Ligands as Active Catalysts for Heck and Suzuki-Miyaura Cross-Coupling Reactions", M. Nonnenmacher, D. Kunz, F. Rominger, T. Oeser, J. Organomet. Chem.* 2007, 692, 2554-2563.
9	"1,8-Bis(imidazolin-2-yliden-1-yl)carbazolide (bimca): A New CNC Pincer-Type Ligand with Strong Electron-Donating Properties. Facile Oxidative Addition of Methyl Iodide to Rh(bimca)(CO)”, M. Moser, B. Wucher, D. Kunz, F. Rominger, Organometallics* 2007, 26, 1024-1030.
8	"X-ray crystal structures of 10π- and 14π-electron pyrido-annelated N-heterocyclic carbenes”, M. Nonnenmacher, D. Kunz, F. Rominger, T. Oeser, Chem. Commun.* 2006, 1378-1380.
7	"First Examples of Dipyrido[1,2-c:2',1'-e]imidazolin-7-ylidenes Serving as NHC-Ligands - Synthesis, Properties and Structural Features of their Chromium and Tungsten Pentacarbonyl Complexes", M. Nonnenmacher, D. Kunz, F. Rominger, T. Oeser, J. Organomet. Chem.* 2005, 690, 5647-5653.

2000 - 2003 (Disstertation, Postdoc)

2000 - 2003 (Disstertation, Postdoc)

6	"Experimental and Computational Evidence for a Boron-Assisted, σ-Bond Metathesis Pathway for Alkane Borylation", C. E. Webster, Y. Fan, M. B. Hall, D. Kunz, J. F. Hartwig, J. Am. Chem. Soc. 2003, 125, 858-859.
5	"Structural Features of Primary 6-Aminopentafulvenes and Some of Their Derivatives", D. Kunz, R. Fröhlich, G. Erker, Eur. J. Org. Chem.* 2001, 3531-3536.
4	"Molybdenum Complexes with Sterically Demanding Cycloheptatrienyl Ligands", M. Tamm, T. Bannenberg, B. Dreßel, R. Fröhlich, D. Kunz, Organometallics* 2001, 20, 900-904.
3	"Preparation and Structural Features of an Aminoacid-derived Cyclopentadienyl Lithium Compound", D. Kunz, R. Fröhlich, G. Erker, Organometallics* 2001, 20, 572-574.
2	"Structural Characterization of M(s-cis-η⁴-C₄H₆) (Me₄C₅SiMe₂NR) (M = Ti or Zr, R = CMe₃ or CHCMe(1-C₁₀H₇)", M. Dahlmann, J. Schottek, R. Fröhlich, D. Kunz, M. Nissinen, G. Erker, G. Fink, R. Kleinschmidt, J. Chem. Soc., Dalton Trans. 2000, 1881-1886.
1	"Reactions of Functional Groups at the Periphery of Group 4 Metallocen Frameworks: Selective Formation of a Cp-Bonded Azaboretidine Derivative by a Hydroboration Route", D. Kunz, G. Erker, R. Fröhlich, G. Kehr, Eur. J. Inorg. Chem.* 2000, 409-416.